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Valspar Plastic Spray Paint, Hunter Green No. 68102
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Plastic Spray PaintStructure such as solid, liquid, aerosol etc.
Form: aerosolDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 2024101 Prospect Avenue
Cleveland OH 44115
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.
UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Isobutyl acetate
000110-19-0
203-745-15.0-10.0 No H225, H336, EUH066 P210, P233, P235, P261, P280, P303+P361+P353, P304+P340, P312 
No No Butane
000106-97-8
203-448-75.0-10.0 No H220, H280 P102, P210, P243, P377, P381, P410+P403 
No No Stoddard solvent
008052-41-3
232-489-35.0-10.0 No H226, H304, H315, H372, H412 P102, P260, P262, P273, P301+P310, P331 
No No Ethyl acetate
000141-78-6
205-500-410.0-15.0 No H225, H319, H336, EUH066 P210, P233, P240, P241, P242, P243, P280, P303+P361+P353, P370+P378, P403+P235, P501,P264, P305+P351+P338, P337+P313, P261, P271, P304+P340, P312, P403+P233, P405 No No Acetone
000067-64-1
200-662-210.0-15.0 No H225, H319, H336, EUH066 P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P304+P340, P305+P351+P328, P312, P337+P313, P403+P233, P405, P501 No No Propane
000074-98-6
200-827-915.0-20.0 No H220, H280 P102, P210, P243, P377, P381, P410+P403 No No Ethylbenzene
000100-41-4
202-849-41.0-5.0 Yes H225, H332 P201, P202, P210, P233, P240, P241, P242, P243, P260, P261, P271, P280, P281, P303+P361+P353, P304+P340, P308+P313, P312, P314, P370+P378, P403+P235, P405, P501 No No 1,2,4-Trimethylbenzene
000095-63-6
202-436-91.0-5.0 No H226, H332, H319, H335, H315, H411 P210, P243, P280, P261, P302+P352, P305+P351+P338, P273, P391 
No No Trade secret or proprietary formula
000000-02-1
---- No -- -- -- No No Isopropanol
000067-63-0
200-661-71.0-5.0 No H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No No Xylene (mixed isomers)
001330-20-7
215-535-75.0-10.0 No H226, H312, H332, H315 P210, P243, P260, P280, P303+P361+P353, P332+P313 No No Methyl acetate
000079-20-9
201-185-25.0-10.0 No H225, H319, H336, EUH066 P210, P243, P280, P271, P304+P340, P312, P305+P351+P338, P337+P313, P403+P233 No No Ethyl 3-ethoxy propionate
000763-69-9
212-112-91.0-5.0 No H226, EUH066 P332+P313, P210, P370+P378, P403+P235, P501 No No Solvent naphtha, petroleum, light aromatic
064742-95-6
265-199-01.0-5.0 No H304, H340, H350 -- No No Titanium dioxide
013463-67-7
236-675-51.0-5.0 No -- -- -- No No -
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Hazard Statements
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- Code
- Statement
- H220 : Extremely flammable gasH225 : Highly flammable liquid and vapourH226 : Flammable liquid and vapourH280 : Contains gas under pressure; may explode if heatedH304 : May be fatal if swallowed and enters airwaysH312 : Harmful in contact with skinH315 : Causes skin irritationH319 : Causes serious eye irritationH332 : Harmful if inhaledH335 : May cause respiratory irritationH336 : May cause drowsiness or dizziness.H340 : May cause genetic defectsH350 : May cause cancer.H372 : Causes damage to organsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effectsEUH066 : Repeated exposure may cause skin dryness or cracking
- P102 : Keep out of reach of childrenP201 : Obtain special instructions before useP202 : Do not handle until all safety precautions have been read and understoodP210 : Keep away from heat/sparks/open flames/hot surfacesP233 : Keep container tightly closedP235 : Keep coolP240 : Ground/bond container and receiving equipmentP241 : Use explosion-proof electrical/ventilating/light/…/equipmentP242 : Use only non-sparking toolsP243 : Take precautionary measures against static dischargeP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP262 : Do not get in eyes, on skin, or on clothingP264 : Wash … thoroughly after handlingP271 : Use only outdoors or in a well-ventilated areaP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP281 : Use personal protective equipment as requiredP312 : Call a POISON CENTER or doctor/physician if you feel unwellP314 : Get Medical advice/attention if you feel unwellP331 : Do NOT induce vomitingP377 : Leaking gas fireP381 : Eliminate all ignition sources if safe to do soP391 : Collect spillageP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP308+P313 : If exposed or concerned: Get medical advice/attentionP332+P313 : If skin irritation occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP370+P378 : In case of fire: Use … for extinctionP405 : Store locked upP501 : Dispose of contents/container to
- GHS02 : FlammableGHS04 : Compressed GasGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :October 21, 2008 Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
MSDS Verified :December 03, 2008 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING2* 4 1 -
V.O.C Information
Volatile Organic Compounds g/L With Solvent : 606
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SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Warnings
DANGER! Extremely flammable liquid and vapor.
Vapors may cause flash fire. Contents under pressure. Vapor harmful.
Not intended for use on soft vinyl, vinyl fabric, or infant toys. Use with adequate ventilation. Contains Dimethyl Ketone, Isobutyl Acetate, Petroleum Distallates, Pseudo Cumene, Ethyl Acetate, Xylene, Ethylbenzene. Vapor Harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Causes eye, skin, nose and throat irritation. Do not puncture or incinerate (burn) container. Exposure to heat or prolonged exposure to sun may cause bursting. Do not expose to heat or store at temperatures above 120 degrees F (49 degrees C.) Replace cap after each use. Vapors may ignite explosively. Keep away from heat sparks and flame. Do not smoke. Extinguish all flames and pilot lights and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation. Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH Approved) during and after application. Follow respirator manufacturer's directions for respirator use. Avoid contact with eyes, skin and clothing. Delayed effect from long term exposure: NOTICE- Reports have associated repeated or prolonged occupational exposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. WARNING: This product contains a chemical known to the State of California to cause cancer. KEEP OUT OF REACH OF CHILDREN. Emergency medical telephone: 1-888-345-5732 -
Acute health effects
From MSDS
HAZARDS IDENTIFICATION
Primary Routes of Exposure: Inhalation; Ingestion; Skin absorption
Eye Contact: Severe eye irritation
Skin Contact: Causes skin irritation. May cause defatting of the skin. Dermatitis. Harmful if absorbed through skin. Can be absorbed through skin.
Ingestion: Irritation of the mouth, throat, and stomach. Harmful if swallowed. Aspiration hazard if swallowed - can enter lungs and cause damage.
Inhalation: Causes respiratory tract irritation. Harmful by inhalation. May cause bronchopneumonia or bronchitis. -
Chronic health effects
From MSDS:
This product contains ingredients that may contribute to the following potential chronic health effects: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. -
Carcinogenicity
Possible cancer hazard. Contains material which may cause cancer based on animal data.
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Contains TIO2 which is listed by IARC as a possible human carcinogen (Group 2B) based on animal data. Neither long term animal studies, nor human epidemiology studies of workers exposed to TIO2 provide an adequate basis to conclude TIO2 is carcinogenic. TIO2 is not classified as a carcinogen by NTP, U.S. OSHA, or the U.S. EPA. -
Handling information
Keep away from heat, sparks and open flame. - No smoking. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. -
Disposal information
Dispose of waste at an approved hazardous waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations. -
California Prop. 65 Warning
WARNING! This product contains a chemical known in the State of California to cause cancer.
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First Aid
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. If medical assistance is not immediately available, flush an additional 15 minutes. Get medical attention immediately.
Skin Contact: Remove contaminated clothing and shoes. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention, if symptoms develop or persist.
Ingestion: Rinse mouth with water. Give one or two glasses of water. Only induce vomiting at the instruction of medical personnel. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than hips to prevent aspiration. Get medical attention immediately.
Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention immediately. For breathing difficulties, oxygen may be necessary. If breathing stops, provide artificial respiration.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
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