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Head and Shoulders Intensive Solutions Dandruff Shampoo, Normal Hair-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: ShampooStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 000100-51-6 -- <0.5 Xn -- -- -- -- 036653-82-4 -- 0.1-1 -- -- -- -- 003486-35-9 -- 0.5-1.5 -- -- -- -- 013463-41-7 -- 0.5-1.5 T, Xi, N -- -- -- -- 000000-00-1 -- -- -- -- -- 009006-65-9 -- -- -- -- -- 007487-88-9 -- -- -- -- -- 000532-32-1 -- -- -- -- -- 068610-92-4 -- -- -- -- -- 012125-28-9 -- -- -- -- -- 032612-48-9 -- -- -- -- -- 007647-14-5 -- -- -- -- -- 026172-55-4 -- -- -- -- -- 002682-20-4 -- -- -- -- -- 026447-10-9 -- -- -- -- -- 004548-53-2 -- -- -- -- -- 003844-45-9 -- <0.5 -- -- -- -- 007732-18-5 -- -- -- -- -- 009004-82-4 -- -- -- -- -- 000151-21-3 -- -- -- -- -- 068140-00-1 -- -- -- -- -- 000627-83-8 -- -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Benzyl alcohol
000100-51-6
202-859-9<0.5 No H302, H332 -- No No Cetyl alcohol
036653-82-4
253-149-00.1-1 No -- -- -- No No Zinc Carbonate
003486-35-9
222-477-60.5-1.5 No H400, H411 P273, P391, P501 No No Zinc pyrithione
013463-41-7
236-671-30.5-1.5 No H301, H331, H318, H400 P264, P270, P261, P271, P280, P273, P301+P310, P330, P304+P340, P311, P305+P351+P338, P310, P501 No No Fragrance(s)/perfume(s)
000000-00-1
---- No -- -- -- No No Dimethicone
009006-65-9
---- No -- -- -- No No Magnesium sulfate
007487-88-9
231-298-2-- No -- -- -- No No Sodium benzoate
000532-32-1
208-534-8-- No H319 P280, P305+P351+P338, P337+P313 No No Polyquaternium-10
068610-92-4
---- No -- -- -- No No Magnesium Carbonate Hydroxide
012125-28-9
235-192-7-- No -- -- -- No No Ammonium laureth sulfate
032612-48-9
---- No -- -- -- No No Sodium chloride
007647-14-5
231-598-3-- No -- -- -- No No Methylchloroisothiazoline
026172-55-4
247-500-7-- No -- -- -- No No Methylisothiazoline
002682-20-4
220-239-6-- No H301, H311, H314, H330, H317, H410, EUH071 -- No No Ammonium xylenesulfonate
026447-10-9
247-710-9-- No -- -- -- No No FD&C Red #4 (C.I. 14700)
004548-53-2
224-909-9-- No -- -- -- No No Acid Blue 9
003844-45-9
223-339-8<0.5 No -- -- -- No No Water
007732-18-5
231-791-2-- No -- -- -- No No Sodium laureth sulfate
009004-82-4
266-192-5-- No -- -- -- No No Sodium lauryl sulfate (SLS)
000151-21-3
205-788-1-- No H302, H315, H318, H412 P264, P280, P301+P312, P330, P302+P352, P305+P351+P338, P310, P321, P332+P313, P362, P273, P501 No No Cocamide MEA
068140-00-1
268-770-2-- No -- -- -- No No Glycol distearate
000627-83-8
211-014-3-- No -- -- -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H301 : Toxic if swallowedH302 : Harmful if swallowedH311 : Toxic in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH317 : May cause an allergic skin reactionH318 : Causes serious eye damageH319 : Causes serious eye irritationH330 : Fatal if inhaledH331 : Toxic if inhaledH332 : Harmful if inhaledH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effectsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effectsEUH071 : Corrosive to the respiratory tract
- P261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP271 : Use only outdoors or in a well-ventilated areaP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP310 : Immediately call a POISON CENTER or doctor/physicianP311 : Call a POISON CENTER or doctor/physicianP321 : Specific treatment (see … on this label)P330 : Rinse mouthP362 : Take off contaminated clothing and wash before reuseP391 : Collect spillageP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP302+P352 : IF ON SKIN: Wash with soap and waterP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP332+P313 : If skin irritation occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP501 : Dispose of contents/container to
- GHS05 : CorrosiveGHS06 : ToxicGHS07 : IrritantGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :February 01, 2008 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Warnings
For external use only. When using this product avoid contact with eyes. If contact occurs, rinse eyes thoroughly with water. Stop use and ask a doctor if condition worsens or does not improve after regular use of this product as directed. Keep this an all drugs out of reach of children. If swallowed, get medical help or contact a Poison Control Center right away. -
Acute health effects
From MSDS:
EMERGENCY OVERVIEW:
This is a personal care or cosmetic product that is safe for consumers and other users under intended and reasonably foreseeable use. Additional information on toxicological endpoints is available from the supplier upon request.
POTENTIAL HEALTH EFFECTS:
Eye: Contact may cause mild, transient irritation. Some redness and/or stinging may occur.
Skin: Not expected to be irritating, sensitizing, photoallergenic or phototoxic when used as intended. If irritation occurs following intended use or prolonged contact it is expected to be mild and transient.
Inhalation: Not expected to be irritating to the respiratory system. Not volatile therefore limited inhalation exposure anticipated.
Ingestion: Product used as intended is not expected to cause gastrointestinal irritation. Accidental ingestion of undiluted product may cause mild gastrointestinal irritation with nausea, vomiting and diarrhea. -
Chronic health effects
From MSDS:
Finished product is not expected to have chronic health effects.
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Carcinogenicity
Finished product is not expected to be carcinogenic.
NTP: No
IARC: No
OSHA: No -
Handling information
Precautions for Safe Handling:
For Household Settings: No applicable information has been found.
For Non-Household Settings: No unusual handling or storage requirements. Storage in large quantities (as in warehouses) should be in a well-ventilated, cool area.
Conditions for Safe Storage:
For Household Settings: No applicable information has been found.
For Non-Household Settings: No unusual handling or storage requirements. Storage in large quantities (as in warehouses) should be in a well-ventilated, cool area. -
Disposal information
Disposal should be in accordance with Federal, State/Provincial and Local regulations.
For Household Settings: The following instructions are for consumer usage only. Do not discharge product into natural waters without pre-treatment or adequate dilution.
For Non-Household Settings: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations.
California Waste Code: 331 -
California Prop. 65 Warning
This product is not subject to warning labeling under California Proposition 65.
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First Aid
Eye: Thorough rinsing for 15-20 minutes of the affected eye with water is recommended. If discomfort or irritation persists, contact a physician.
Skin Problem: Discontinue use of product. Apply cold compresses to affected areas to relieve any discomfort. If discomfort persists, contact a physician.
Inhalation: If respiratory irritation occurs, remove individual to fresh air.
Ingestion: Accidental ingestion of product may necessitate medical attention. In case of accidental ingestion dilute with fluids (water or milk) and treat symptomatically. Do not induce vomiting.
Note: After first aid treatment, the caller should be advised that 1) a hospital emergency room or family physician should be consulted if anything unusual occurs or appears necessary in the judgment of the caller, and 2) that the subsequent management of the accident should be dictated by any persistent symptoms and under the direction of the physician.
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