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Head and Shoulders Dandruff Shampoo, Citrus Breeze-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: ShampooStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)Benzyl alcohol 000100-51-6 <0.5 Yes CoC List Cetyl alcohol 036653-82-4 0.1-1 Yes CoC List Zinc Carbonate 003486-35-9 0.5-1.5 No Zinc pyrithione 013463-41-7 0.5-1.5 Yes CoC List Fragrance(s)/perfume(s) 000000-00-1 -- No Dimethicone 009006-65-9 -- No Magnesium sulfate 007487-88-9 -- No Sodium benzoate 000532-32-1 -- No Hydroxypropyltrimonium chloride 065497-29-2 -- No Magnesium Carbonate Hydroxide 012125-28-9 -- No Ammonium laureth sulfate 032612-48-9 -- No Sodium chloride 007647-14-5 -- No Methylchloroisothiazoline 026172-55-4 -- No Methylisothiazoline 002682-20-4 -- No FD&C (or D&C) Yellow #5 (C.I. 19140) 001934-21-0 -- No Grapefruit extract 090045-43-5 -- No Camellia sinensis extract 084650-60-2 -- No Sodium xylenesulfonate 001300-72-7 -- No Acid Blue 9 003844-45-9 <0.5 No Water 007732-18-5 -- No Sodium laureth sulfate 009004-82-4 -- No Sodium lauryl sulfate (SLS) 000151-21-3 -- No Cocamide MEA 068140-00-1 -- No Glycol distearate 000627-83-8 -- No Cymbopogon schoenanthus 089998-16-3 -- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Benzyl alcohol 000100-51-6 202-859-9 <0.5 H302, H332 ------- No Cetyl alcohol 036653-82-4 253-149-0 0.1-1 -------- ------- ---- No Zinc Carbonate 003486-35-9 222-477-6 0.5-1.5 H400, H411 P273, P391, P501 No Zinc pyrithione 013463-41-7 236-671-3 0.5-1.5 H301, H331, H318, H400 P264, P270, P261, P271, P280, P273, P301+P310, P330, P304+P340, P311, P305+P351+P338, P310, P501 No Fragrance(s)/perfume(s) 000000-00-1 -- -- -------- ------- ---- No Dimethicone 009006-65-9 -- -- -------- ------- ---- No Magnesium sulfate 007487-88-9 231-298-2 -- -------- ------- ---- No Sodium benzoate 000532-32-1 208-534-8 -- H319 P280, P305+P351+P338, P337+P313 No Hydroxypropyltrimonium chloride 065497-29-2 - -- -------- ------- ---- Yes Magnesium Carbonate Hydroxide 012125-28-9 235-192-7 -- -------- ------- ---- No Ammonium laureth sulfate 032612-48-9 -- -- -------- ------- ---- No Sodium chloride 007647-14-5 231-598-3 -- -------- ------- ---- No Methylchloroisothiazoline 026172-55-4 247-500-7 -- -------- ------- ---- No Methylisothiazoline 002682-20-4 220-239-6 -- H301, H311, H314, H330, H317, H410, EUH071 ------- No FD&C (or D&C) Yellow #5 (C.I. 19140) 001934-21-0 217-699-5 -- -------- ------- ---- No Grapefruit extract 090045-43-5 289-904-6 -- H226, H304, H315, H317, H411 P210, P241, P261, P262, P280, P273, P301+P310, P303+P361+P353, P331, P405, P501, P391 No Camellia sinensis extract 084650-60-2 283-519-7 -- -------- ------- ---- No Sodium xylenesulfonate 001300-72-7 215-090-9 -- -------- ------- ---- No Acid Blue 9 003844-45-9 223-339-8 <0.5 -------- ------- ---- No Water 007732-18-5 231-791-2 -- -------- ------- ---- No Sodium laureth sulfate 009004-82-4 266-192-5 -- -------- ------- ---- No Sodium lauryl sulfate (SLS) 000151-21-3 205-788-1 -- H302, H315, H318, H412 P264, P280, P301+P312, P330, P302+P352, P305+P351+P338, P310, P321, P332+P313, P362, P273, P501 No Cocamide MEA 068140-00-1 268-770-2 -- -------- ------- ---- No Glycol distearate 000627-83-8 211-014-3 -- -------- ------- ---- No Cymbopogon schoenanthus 089998-16-3 289-754-1 -- -------- ------- ---- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :January 01, 2008 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
Warnings
For external use only. When using this product avoid contact with eyes. If contact occurs, rinse eyes thoroughly with water. Stop use and ask a doctor if condition worsens or does not improve after regular use of this product as directed. Keep this an all drugs out of reach of children. If swallowed, get medical help or contact a Poison Control Center right away. -
Acute health effects
From MSDS:
EMERGENCY OVERVIEW:
This is a personal care or cosmetic product that is safe for consumers and other users under intended and reasonably foreseeable use. Additional information on toxicological endpoints is available from the supplier upon request.
POTENTIAL HEALTH EFFECTS:
Eye: Contact may cause mild, transient irritation. Some redness and/or stinging may occur.
Skin: Not expected to be irritating, sensitizing, photoallergenic or phototoxic when used as intended. If irritation occurs following intended use or prolonged contact it is expected to be mild and transient.
Inhalation: Not expected to be irritating to the respiratory system. Not volatile therefore limited inhalation exposure anticipated.
Ingestion: Product used as intended is not expected to cause gastrointestinal irritation. Accidental ingestion of undiluted product may cause mild gastrointestinal irritation with nausea, vomiting and diarrhea. -
Chronic health effects
From MSDS:
Finished product is not expected to have chronic health effects.
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Carcinogenicity
Finished product is not expected to be carcinogenic.
NTP: No
IARC: No
OSHA: No -
Handling information
Precautions for Safe Handling:
For Household Settings: No applicable information has been found.
For Non-Household Settings: No unusual handling or storage requirements. Storage in large quantities (as in warehouses) should be in a well-ventilated, cool area.
Conditions for Safe Storage:
For Household Settings: No applicable information has been found.
For Non-Household Settings: No unusual handling or storage requirements. Storage in large quantities (as in warehouses) should be in a well-ventilated, cool area. -
Disposal information
Disposal should be in accordance with Federal, State/Provincial and Local regulations.
For Household Settings: The following instructions are for consumer usage only. Do not discharge product into natural waters without pre-treatment or adequate dilution.
For Non-Household Settings: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations.
California Waste Code: 331 -
California Prop. 65 Warning
This product is not subject to warning labeling under California Proposition 65.
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First Aid
Eye: Thorough rinsing for 15-20 minutes of the affected eye with water is recommended. If discomfort or irritation persists, contact a physician.
Skin Problem: Discontinue use of product. Apply cold compresses to affected areas to relieve any discomfort. If discomfort persists, contact a physician.
Inhalation: If respiratory irritation occurs, remove individual to fresh air.
Ingestion: Accidental ingestion of product may necessitate medical attention. In case of accidental ingestion dilute with fluids (water or milk) and treat symptomatically. Do not induce vomiting.
Note: After first aid treatment, the caller should be advised that 1) a hospital emergency room or family physician should be consulted if anything unusual occurs or appears necessary in the judgment of the caller, and 2) that the subsequent management of the accident should be dictated by any persistent symptoms and under the direction of the physician.
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