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CPID

Health effects of consumer products

Baldessarini Men's Eau de Cologne Spray-03/01/2008

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Back

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  REACH COMPLIANCE
  EU Hazard Classification Directive 67/548/EEC

  Hazard Symbols are used to classify dangerous substances.

  Hazard Symbols

  Risk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.

  Risk Phrases

  Safety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.

  Safety Phrases

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  --	000106-22-9	--		Xi, N	--	--	--
  --	005392-40-5	--		Xi	--	--	--
  --	000104-55-2	--			--	--	--
  --	000118-58-1	--			--	--	--
  --	000103-41-3	--			--	--	--
  --	000120-51-4	--		Xn, N	--	--	--
  --	000100-51-6	--		Xn	--	--	--
  --	000105-13-5	--			--	--	--
  --	000101-85-9	--			--	--	--
  --	004602-84-0	--			--	--	--
  --	000106-24-1	--		Xi	--	--	--
  --	000107-75-5	--			--	--	--
  --	000097-54-1	--			--	--	--
  --	000000-58-7	--			--	--	--
  --	000138-86-3	--		Xi, N	--	--	--
  --	000078-70-6	--		Xi	--	--	--
  --	000111-12-6	--			--	--	--
  --	000127-51-5	--			--	--	--
  --	090028-68-5	--			--	--	--
  --	000122-40-7	--			--	--	--
  --	000000-03-2	--			--	--	--
  --	012001-26-2	--			--	--	--
  --	000057-55-6	--			--	--	--
  --	070356-09-1	--			--	--	--
  --	085711-69-9	--		Xn	--	--	--
  --	068201-46-7	--			--	--	--
  --	063793-60-2	--			--	--	--
  --	002783-94-0	--			--	--	--
  --	003567-66-6	--			--	--	--
  --	004548-53-2	--			--	--	--
  --	003844-45-9	--			--	--	--
  --	008004-92-0	--			--	--	--
  --	001310-73-2	--		C	--	--	--
  --	000050-21-5	--		Xi	--	--	--
  --	000131-55-5	--			--	--	--
  --	000097-59-6	--			--	--	--
  --	061788-85-0	--			--	--	--
  --	361459-38-3	--			--	--	--
  --	000000-00-1	--			--	--	--
  --	007732-18-5	--			--	--	--
  --	000064-17-5	--	60-100		--	--	--
  --	000081-48-1	--			--	--	--
  --	004403-90-1	--			--	--	--
  --	001934-21-0	--			--	--	--
  --	999999-61-8	--			--	--	--
  --	999999-60-2	--			--	--	--
  --	013463-67-7	--			--	--	--
  --	000128-37-0	--			--	--	--
  --	000099-76-3	--			--	--	--
  --	000081-13-0	--			--	--	--
  --	000139-33-3	--			--	--	--
  --	000118-60-5	--			--	--	--
  --	068797-35-3	--			--	--	--
  --	000079-50-5	--			--	--	--
  --	090028-67-4	--			--	--	--
  --	000091-64-5	--			--	--	--
  --	000097-53-0	--			--	--	--

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  California Prop.65 Chemical?

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Endocrine Disruptor (ED)

  Citronellol
  000106-22-9 203-375-0	--	No	H315, H317, H319 -- No No
  Citral
  005392-40-5 226-394-6	--	No	H319, H315, H317 -- No No
  Cinnamaldehyde
  000104-55-2 203-213-9	--	No	H315, H317, H319, H412 -- No No
  Benzyl Salicylate
  000118-58-1 204-262-9	--	No	H317, H319, H412 P260, P264, P272, P273, P280, P302+P352, P305+P351+P338, P307+P311, P333+P313, P337+P313, P362, P405, P501 No No
  Benzyl Cinnamate
  000103-41-3 203-109-3	--	No	H317, H410 P272, P273, P280, P302+P352, P333+P313, P362+P364 No No
  Benzyl Benzoate
  000120-51-4 204-402-9	--	No	H302, H400, H412 -- No No
  Benzyl alcohol
  000100-51-6 202-859-9	--	No	H302, H332 -- No No
  Anisyl alcohol
  000105-13-5 203-273-6	--	No	H302, H315, H317 -- No No
  Amylcinnamyl Alcohol
  000101-85-9 202-982-8	--	No	-- -- -- No No
  Farnesol
  004602-84-0 225-004-1	--	No	H315, H317, H410 P264, P272, P273, P280, P302+P352, P333+P313 No No
  Geraniol
  000106-24-1 203-377-1	--	No	H315, H317, H318 -- No No
  Hydroxycitronellal
  000107-75-5 203-518-7	--	No	H319, H317 -- No No
  Isoeugenol
  000097-54-1 202-590-7	--	No	-- -- -- No No
  Butylphenyl Methylpropional-1
  000000-58-7 --	--	No	-- -- -- No No
  Dipentene
  000138-86-3 205-341-0	--	No	H226, H315, H317, H400, H410 -- No No
  Linalool
  000078-70-6 201-134-4	--	No	H315, H317, H319 P280 No No
  Methyl 2 -Octynoate
  000111-12-6 203-836-6	--	No	H412, H400, H317 P391, P273, P333+P313, P261 No No
  alpha-Isomethyl ionone
  000127-51-5 204-846-3	--	No	H411 P273, P391, P501 No No
  Evernia Prunastri
  090028-68-5 289-861-3	--	No	H315, H317, H319 P101, P102, P103, P261, P280, P302+P352, P305+P351+P338, P362+P364, P501 No No
  Amyl Cinnamal
  000122-40-7 204-541-5	--	No	H400, H410 P273, P391, P501 No No
  PEG-16 soy sterol
  000000-03-2 --	--	No	-- -- -- No No
  Mica
  012001-26-2 -	--	No	-- -- -- Yes No
  Propylene glycol
  000057-55-6 200-338-0	--	No	-- -- -- No No
  Avobenzone
  070356-09-1 274-581-6	--	No	-- -- No No
  Secondary alkane sulphonate
  085711-69-9 288-330-3	--	No	-- -- -- No No
  PEG-7 Glyceryl Cocoate
  068201-46-7 --	--	No	-- -- -- No No
  PPG-3 myristyl ether
  063793-60-2 --	--	No	-- -- -- No No
  FD&C Yellow #6 (C.I. 15985)
  002783-94-0 220-491-7	--	No	-- -- -- No No
  FD&C Red #33
  003567-66-6 222-656-9	--	No	-- -- -- No No
  FD&C Red #4 (C.I. 14700)
  004548-53-2 224-909-9	--	No	-- -- -- No No
  Acid Blue 9
  003844-45-9 223-339-8	--	No	-- -- -- No No
  FD&C (or D&C) Yellow #10 (C.I. 47005)
  008004-92-0 305-632-3	--	No	H411 -- No No
  Sodium hydroxide
  001310-73-2 215-185-5	--	No	H290, H314, H315, H319 P260, P280, P303+P361+P353, P305+P351+P338, P310 No No
  Lactic acid
  000050-21-5 200-018-0	--	No	H315, H318 P264, P280, P302+P352, P305+P351+P338, P310, P321, 332+P313, P362 No No
  Benzophenone-2
  000131-55-5 205-028-9	--	No	-- -- -- No No
  Allantoin
  000097-59-6 202-592-8	--	No	-- -- -- No No
  PEG-40 hydrogenated castor oil
  061788-85-0 500-147-5	--	No	-- -- -- No No
  PEG-6 Caprylic/capric glycerides
  361459-38-3 --	--	No	-- -- -- No No
  Fragrance(s)/perfume(s)
  000000-00-1 --	--	No	-- -- -- No No
  Water
  007732-18-5 231-791-2	--	No	-- -- -- No No
  SD Alcohol 38B
  000064-17-5 200-578-6	60-100	No	H225, H319 P210, P233, P240, P241, P242, P243, P264, P280, P303+P361+P353, P370+P378, P305+P351+P338, P337+P313, P403+P235, P501 No No
  D&C Violet # 2
  000081-48-1 201-353-5	--	No	H317, H413 -- No No
  D&C Green #5 (C.I. 61570)
  004403-90-1 224-546-6	--	No	H413 -- -- No No
  FD&C (or D&C) Yellow #5 (C.I. 19140)
  001934-21-0 217-699-5	--	No	-- -- -- No No
  Silica (unspecified)
  999999-61-8 --	--	No	-- -- -- No No
  Iron oxide(s) (unspecified)
  999999-60-2 --	--	No	-- -- -- No No
  Titanium dioxide
  013463-67-7 236-675-5	--	No	-- -- -- No No
  2,6-Di-t-butyl-p-cresol (BHT)
  000128-37-0 204-881-4	--	No	H410 -- No No
  Methylparaben
  000099-76-3 202-785-7	--	No	H411 P273, P391, P501 No No
  Panthenol
  000081-13-0 201-327-3	--	No	-- -- -- No No
  Disodium EDTA
  000139-33-3 205-358-3	--	No	-- -- -- No No
  Octisalate
  000118-60-5 204-263-4	--	No	H410 P273, P391, P501 No No
  Dipotassium glycyrrhizate
  068797-35-3 272-296-1	--	No	-- -- -- No No
  Pantolactone
  000079-50-5 201-210-7	--	No	H319 -- No No
  Evernia Furfuracea
  090028-67-4 289-860-8	--	No	H317, H319 P101, P102, P103, P261, P280, P302+P352, P305+P351+P338, P362+P364, P501 No No
  Coumarin
  000091-64-5 202-086-7	--	No	H301, H311, H317, H411 P260, P261, P264, P270, P272, P273, P280, P321, P363, P301+P312, P302+P352, P333+P313, P501 No No
  Eugenol
  000097-53-0 202-589-1	--	No	H319, H317 P261, P264, P272, P280, P302+P352, P305+P351+P338, P333+P313, P337+P313, P363, P501 No No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Hazard Statements

    • • Code
      • Statement
    • H225 : Highly flammable liquid and vapour
      H226 : Flammable liquid and vapour
      H290 : May be corrosive to metals
      H301 : Toxic if swallowed
      H302 : Harmful if swallowed
      H311 : Toxic in contact with skin
      H314 : Causes severe skin burns and eye damage
      H315 : Causes skin irritation
      H317 : May cause an allergic skin reaction
      H318 : Causes serious eye damage
      H319 : Causes serious eye irritation
      H332 : Harmful if inhaled
      H400 : Very toxic to aquatic life
      H410 : Very toxic to aquatic life with long lasting effects
      H411 : Toxic to aquatic life with long lasting effects
      H412 : Harmful to aquatic life with long lasting effects
      H413 : May cause long lasting harmful effects to aquatic life
    • P101 : If medical advice is needed, have product container or label at hand
      P102 : Keep out of reach of children
      P103 : Read label before use
      P210 : Keep away from heat/sparks/open flames/hot surfaces
      P233 : Keep container tightly closed
      P240 : Ground/bond container and receiving equipment
      P241 : Use explosion-proof electrical/ventilating/light/…/equipment
      P242 : Use only non-sparking tools
      P243 : Take precautionary measures against static discharge
      P260 : Do not breathe dust/fume/gas/mist/vapours/spray
      P261 : Avoid breathing dust/fume/gas/mist/vapours/spray
      P264 : Wash … thoroughly after handling
      P270 : Do not eat, drink or smoke when using this product
      P272 : Contaminated work clothing should not be allowed out of the workplace
      P273 : Avoid release to the environment
      P280 : Wear protective gloves/protective clothing/eye protection/face protection
      P310 : Immediately call a POISON CENTER or doctor/physician
      P321 : Specific treatment (see … on this label)
      P362 : Take off contaminated clothing and wash before reuse
      P363 : Wash contaminated clothing before reuse
      P391 : Collect spillage
      P301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
      P302+P352 : IF ON SKIN: Wash with soap and water
      P303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
      P305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do
      P307+P311 : If exposed: Call a POISON CENTER or doctor/physician
      P333+P313 : If skin irritation or a rash occurs: Get medical advice/attention
      P337+P313 : Get medical advice/attention
      P370+P378 : In case of fire: Use … for extinction
      P405 : Store locked up
      P501 : Dispose of contents/container to
    • GHS02 : Flammable
      GHS05 : Corrosive
      GHS07 : Irritant
      GHS08 : Health Hazard
      GHS09 : Environmentally Hazardous
  • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      March 01, 2008

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • SVHC declaration

      Warning: This product contains Substances of Very High Concern (SVHC).

    • Acute health effects

      From MSDS:
      EMERGENCY OVERVIEW:
      This is a personal care or cosmetic product that is safe for consumers and other users under intended and reasonably foreseeable use. Additional information on toxicological endpoints is available from the supplier upon request.
      POTENTIAL HEALTH EFFECTS:
      • Eye: Contact may cause mild, transient irritation. Some redness and/or stinging may occur.
      • Skin: Not expected to be irritating, sensitizing, photoallergenic or phototoxic when used as intended. If irritation occurs following intended use or prolonged contact it is expected to be mild and transient.
      • Inhalation: Not expected to be irritating to the respiratory system. Not volatile therefore limited inhalation exposure anticipated.
      • Ingestion: Product used as intended is not expected to cause gastrointestinal irritation. Accidental ingestion of undiluted product may cause mild gastrointestinal irritation with nausea, vomiting and diarrhea.

    • Chronic health effects

      From MSDS:
      Finished product is not expected to have chronic health effects.
      

    • Carcinogenicity

      Finished product is not expected to be carcinogenic.
      NTP: No IARC: No OSHA: No

    • Handling information

      For Household Settings: Do not expose to heat and flame.
      For Non-Household Settings: Avoid heat, sparks, flame, or smoking during use. Avoid extreme heat and ignition sources. Avoid spraying toward open flame.
      • Conditions for Safe Storage:
      For Household Settings: Avoid heat, sparks, flame, or smoking. Avoid extreme heat and ignition sources. Store away from oxidizers. Store between 41-95

    • Disposal information

      Disposal should be in accordance with Federal, State/Provincial and Local regulations.
      For Household Settings: The following instructions are for consumer usage only. Do not discharge product into natural waters without pre-treatment or adequate dilution. Keep product closed to avoid volatilization.
      For Non-Household Settings: Products covered by this MSDS, in their original form, when disposed as waste, are ignitable hazardous waste, D001, according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations. California Waste Code: 331

    • California Prop. 65 Warning

      This product is not subject to warning labeling under California Proposition 65.

    • First Aid

      • Eye: Thorough rinsing for 15-20 minutes of the affected eye with water is recommended. If discomfort or irritation persists, contact a physician.
      • Skin Problem: Discontinue use of product. Apply cold compresses to affected areas to relieve any discomfort. If discomfort persists, contact a physician.
      • Inhalation: If respiratory irritation occurs, remove individual to fresh air.
      • Ingestion: Accidental ingestion of product may necessitate medical attention. In case of accidental ingestion dilute with fluids (water or milk) and treat symptomatically. Do not induce vomiting.
      Note: After first aid treatment, the caller should be advised that 1) a hospital emergency room or family physician should be consulted if anything unusual occurs or appears necessary in the judgment of the caller, and 2) that the subsequent management of the accident should be dictated by any persistent symptoms and under the direction of the physician.