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Clairol Mens Choice Haircolor, Natural Black-12/20/2002-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Hair DyeStructure such as solid, liquid, aerosol etc.
Form: kitDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)1-Acetoxy-2-Methylnaphthalene 005697-02-9 Colorant No Oleamide MIPA 000111-05-7 Colorant No Steareth-21 009005-00-9 Developer No Propylene glycol 000057-55-6 Colorant Yes CoC List Oleth-10 024871-34-9 Colorant No Behentrimonium chloride 017301-53-0 Colorant Yes CoC List Sodium carbonate 000497-19-8 Colorant No Decyl beta-D-glucopyranoside 058846-77-8 Colorant No Dihydroxypropyl PEG-5 Linoleammonium chloride 168677-75-6 Colorant No Soytrimonium chloride 061790-41-8 Colorant No Hydroxyethyl cellulose 009004-62-0 Colorant No 1-Hydroxyethyl 4,5-diamino pyrazole sulfate 155601-30-2 Colorant No Ascorbic Acid (Vitamin C) 000050-81-7 Colorant No C11-15 pareth-9 068131-40-8 Colorant No Dilinoleic acid 006144-28-1 Colorant No Fragrance(s)/perfume(s) 000000-00-1 Colorant No C12-15 Pareth-3 068131-39-5 Developer No PEG-50 hydrogenated palmamide 000000-73-6 Developer No Laureth-23 009002-92-0 Colorant No Acrylates copolymer 000000-45-9 Developer No Oleth-2 005274-65-7 Developer No Oleth-5 005353-27-5 Developer No Acrylates/Steareth-20 Methacrylate copolymer 000000-50-0 Developer No Glyceryl monostearate 031566-31-1 Developer No PEG-5 tallow amide 008051-63-6 Developer No Hydrogen peroxide 007722-84-1 Developer Yes CoC List Nonoxynol-9 026571-11-9 Developer Yes CoC List Isopropyl palmitate 000142-91-6 Developer No Cetyl alcohol 036653-82-4 Developer Yes CoC List Nonoxynol-4 007311-27-5 Developer Yes CoC List Ceteareth 80 068439-49-6 Developer No Cocamide MEA 068140-00-1 Colorant No PEG-80 sorbitan laurate 009005-64-5 Developer No Monoethanolamine (MEA) 000141-43-5 Colorant Yes CoC List p-Aminophenol 000123-30-8 Colorant No Cetostearyl alcohol 067762-27-0 Developer No Cocoamidopropylbetaine 061789-40-0 Colorant No Olealkonium chloride 037139-99-4 Colorant No 3-Aminophenol 000591-27-5 Colorant No Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt) 058262-44-5 Colorant No p-Phenylenediamine 000106-50-3 Colorant Yes CoC List Isopropanol 000067-63-0 Colorant Yes CoC List Diethylene glycol ethyl ether 000111-90-0 Colorant No Hexylene glycol 000107-41-5 Colorant No Nonoyl Nonoxynol-49 009014-93-1 Colorant No Oleic acid 000112-80-1 Colorant No Citric acid 000077-92-9 Colorant No 4-Amino-2-hydroxytoluene 002835-95-2 Colorant No Resorcinol 000108-46-3 Colorant Yes CoC List Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).1-Acetoxy-2-Methylnaphthalene 005697-02-9 454-690-7 Colorant -------- ------- ---- No Oleamide MIPA 000111-05-7 203-828-2 Colorant H411, H317 ------- No Steareth-21 009005-00-9 500-017-8 Developer -------- ------- ---- No Propylene glycol 000057-55-6 200-338-0 Colorant -------- ------- ---- No Oleth-10 024871-34-9 -- Colorant -------- ------- ---- No Behentrimonium chloride 017301-53-0 241-327-0 Colorant -------- ------- ---- No Sodium carbonate 000497-19-8 207-838-8 Colorant H319 P264, P280, P305+P351+P338, P337+313 No Decyl beta-D-glucopyranoside 058846-77-8 -- Colorant -------- ------- ---- No Dihydroxypropyl PEG-5 Linoleammonium chloride 168677-75-6 -- Colorant -------- ------- ---- No Soytrimonium chloride 061790-41-8 263-134-0 Colorant H302, H314, H400, H410, EUH071 ------- No Hydroxyethyl cellulose 009004-62-0 - Colorant -------- ------- ---- Yes 1-Hydroxyethyl 4,5-diamino pyrazole sulfate 155601-30-2 429-300-3 Colorant H317, H318, H411 P261, P273, P280, P302+P352 No Ascorbic Acid (Vitamin C) 000050-81-7 200-066-2 Colorant -------- ------- ---- No C11-15 pareth-9 068131-40-8 614-295-4 Colorant -------- ------- ---- No Dilinoleic acid 006144-28-1 -- Colorant -------- ------- ---- No Fragrance(s)/perfume(s) 000000-00-1 -- Colorant -------- ------- ---- No C12-15 Pareth-3 068131-39-5 500-195-7 Developer -------- ------- ---- No PEG-50 hydrogenated palmamide 000000-73-6 -- Developer -------- ------- ---- No Laureth-23 009002-92-0 500-002-6 Colorant -------- ------- ---- No Acrylates copolymer 000000-45-9 -- Developer -------- ------- ---- No Oleth-2 005274-65-7 -- Developer -------- ------- ---- No Oleth-5 005353-27-5 -- Developer -------- ------- ---- No Acrylates/Steareth-20 Methacrylate copolymer 000000-50-0 -- Developer -------- ------- ---- No Glyceryl monostearate 031566-31-1 250-705-4 Developer -------- ------- ---- No PEG-5 tallow amide 008051-63-6 -- Developer -------- ------- ---- No Hydrogen peroxide 007722-84-1 231-765-0 Developer H271, H302, H314, H332, H335, H412 ------- No Nonoxynol-9 026571-11-9 247-816-5 Developer -------- ------- ---- Yes Isopropyl palmitate 000142-91-6 205-571-1 Developer -------- ------- ---- No Cetyl alcohol 036653-82-4 253-149-0 Developer -------- ------- ---- No Nonoxynol-4 007311-27-5 -- Developer -------- ------- ---- Yes Ceteareth 80 068439-49-6 939-518-5 Developer -------- ------- ---- No Cocamide MEA 068140-00-1 268-770-2 Colorant -------- ------- ---- No PEG-80 sorbitan laurate 009005-64-5 500-018-3 Developer -------- ------- ---- No Monoethanolamine (MEA) 000141-43-5 205-483-3 Colorant H302, H312, H332, H314, H335, H412 P273, P501 No p-Aminophenol 000123-30-8 204-616-2 Colorant H302, H317, H332, H341, H373, H410 P202, P261, P273, P281, P302+P352:, P304+P340, P308+P313, P501 No Cetostearyl alcohol 067762-27-0 267-008-6 Developer -------- P101, P102, P280, P301+P312, P302+P352, P305+P351+P338 ---- No Cocoamidopropylbetaine 061789-40-0 263-058-8 Colorant H315, H319, H317, H412 ------- No Olealkonium chloride 037139-99-4 253-363-4 Colorant -------- ------- ---- No 3-Aminophenol 000591-27-5 209-711-2 Colorant H411, H400, H317, H302, H332 P264, P270, P301+P312, P330, P261, P271 No Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt) 058262-44-5 -- Colorant -------- ------- ---- No p-Phenylenediamine 000106-50-3 203-404-7 Colorant H301, H311, H331, H370, H319, H317, H410 P264, P270, P273, P311, P321, P391, P403+P233, P405, P501, P301+P310, P330, P305+P351+P338, P337+P313, P272, P302+P352, P333+P313, P363 No Isopropanol 000067-63-0 200-661-7 Colorant H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No Diethylene glycol ethyl ether 000111-90-0 203-919-7 Colorant -------- ------- ---- No Hexylene glycol 000107-41-5 203-489-0 Colorant H315, H319 ------- No Nonoyl Nonoxynol-49 009014-93-1 - Colorant -------- ------- ---- Yes Oleic acid 000112-80-1 204-007-1 Colorant -------- ------- ---- No Citric acid 000077-92-9 201-069-1 Colorant H319 P264, P280, P305, P351, P338, P337, P313 No 4-Amino-2-hydroxytoluene 002835-95-2 220-618-6 Colorant H226, H336, H412 ------- No Resorcinol 000108-46-3 108-46-3 Colorant H302, H315, H319, H400 ------- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :December 20, 2002 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
Warnings
Haircolor products can cause allergic reactions which in rare cases can be Severe. Tattoos may increase your risk of allergy to this product. Conduct a skin allergy test 48 hours before each time you color even if you have already used coloring products before. So remember to buy the product 48 hours in advance. Do not use the product at all if: •You have already experienced any reaction to haircolor products •You have sensitive, irritated or damaged scalp In these cases, consult a doctor before dying your hair with any haircolor product. Read and follow instructions on enclosed leaflet. In rare cases, use of hair colorants has been associated with skin depigmentation (skin lightening or loss of color). This may be temporary or permanent. If you notice any skin depigmentation or other allergic reaction such as pain or severe itching, discontinue use immediately. -
Acute health effects
From MSDS HEALTH HAZARDS AND HAZARD DATA FOR THE COLORANT-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide), the mixture may cause severe irritation and possible permanent eye injury. SKIN CONTACT: May cause skin irritation or sensitization in sensitized individuals. INHALATION: Inhalation of vapors may result in respiratory irritation. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HEALTH HAZARDS AND HAZARD DATA FOR THE DEVELOPER-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. SKIN CONTACT: Prolonged contact with skin may bleach it and cause burns. INHALATION: Not likely to be inhaled. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. -
Chronic health effects
From MSDS HAZARD DATA FOR THE COLORANT A composite mixture of oxidative dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HAZARD DATA FOR THE DEVELOPER When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin Pre-existing dermatitis would likely be made worse by exposure to these products. -
Carcinogenicity
From MSDS Not listed as carcinogen by NTP, IARC or OSHA. -
Handling information
From MSDS COLORANT Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. DEVELOPER Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat sparks and flame. Do not store any tint, lightener, lotion or bleach powder after it has been mixed with developer; container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. -
Disposal information
From MSDS Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations. -
First Aid
From MSDS Eye Contact: Remove contact lenses. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center.
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