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CPID

Health effects of consumer products

Clairol Mens Choice Haircolor, Natural Dark Brown-12/20/2002-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  1-Acetoxy-2-Methylnaphthalene	005697-02-9	Colorant		No
  Oleamide MIPA	000111-05-7	Colorant		No
  Steareth-21	009005-00-9	Developer		No
  Propylene glycol	000057-55-6	Colorant		Yes  NY-11: NTP Reproductive or Developmental Toxicant NY-26: New York DOH MCL CA-12-NTP Reproductive or Developmental Toxicants  CoC List
  Oleth-10	024871-34-9	Colorant		No
  Behentrimonium chloride	017301-53-0	Colorant		Yes  NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals  CoC List
  Sodium carbonate	000497-19-8	Colorant		No
  Decyl beta-D-glucopyranoside	058846-77-8	Colorant		No
  Dihydroxypropyl PEG-5 Linoleammonium chloride	168677-75-6	Colorant		No
  Soytrimonium chloride	061790-41-8	Colorant		No
  Hydroxyethyl cellulose	009004-62-0	Colorant		No
  1-Hydroxyethyl 4,5-diamino pyrazole sulfate	155601-30-2	Colorant		No
  Ascorbic Acid (Vitamin C)	000050-81-7	Colorant		No
  C11-15 pareth-9	068131-40-8	Colorant		No
  Dilinoleic acid	006144-28-1	Colorant		No
  Fragrance(s)/perfume(s)	000000-00-1	Colorant		No
  C12-15 Pareth-3	068131-39-5	Developer		No
  PEG-50 hydrogenated palmamide	000000-73-6	Developer		No
  Laureth-23	009002-92-0	Colorant		No
  Acrylates copolymer	000000-45-9	Developer		No
  Oleth-2	005274-65-7	Developer		No
  Oleth-5	005353-27-5	Developer		No
  Acrylates/Steareth-20 Methacrylate copolymer	000000-50-0	Developer		No
  Glyceryl monostearate	031566-31-1	Developer		No
  PEG-5 tallow amide	008051-63-6	Developer		No
  Hydrogen peroxide	007722-84-1	Developer		Yes  NY-23: AOEC Asthmagens  CoC List
  Nonoxynol-9	026571-11-9	Developer		Yes  NY-03: EU-SVHC-Endocrine Disruptor Chemical CA-03: EU-SVHC-Endocrine Disruptor Chemical  CoC List
  Isopropyl palmitate	000142-91-6	Developer		No
  Cetyl alcohol	036653-82-4	Developer		Yes  NY-24: U.S. EPA TSCA Chemical of Concern  CoC List
  Nonoxynol-4	007311-27-5	Developer		Yes  NY-03: EU-SVHC-Endocrine Disruptor Chemical CA-03: EU-SVHC-Endocrine Disruptor Chemical CA-22-OSPAR Conventions for Protection of Marine Environment of North-East Atlantic, Priority Chemicals Ny-21: OSPAR Priority Chemicals  CoC List
  Ceteareth 80	068439-49-6	Developer		No
  Cocamide MEA	068140-00-1	Colorant		No
  PEG-80 sorbitan laurate	009005-64-5	Developer		No
  Monoethanolamine (MEA)	000141-43-5	Colorant		Yes  NY-23: AOEC Asthmagens  CoC List
  p-Aminophenol	000123-30-8	Colorant		No
  Cetostearyl alcohol	067762-27-0	Developer		No
  Cocoamidopropylbetaine	061789-40-0	Colorant		No
  Olealkonium chloride	037139-99-4	Colorant		No
  3-Aminophenol	000591-27-5	Colorant		No
  Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt)	058262-44-5	Colorant		No
  p-Phenylenediamine	000106-50-3	Colorant		Yes  NY-17: California Toxic Air Contaminant Chemicals (TACs) CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Isopropanol	000067-63-0	Colorant		Yes  CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  Diethylene glycol ethyl ether	000111-90-0	Colorant		No
  Hexylene glycol	000107-41-5	Colorant		No
  Nonoyl Nonoxynol-49	009014-93-1	Colorant		No
  Oleic acid	000112-80-1	Colorant		No
  Citric acid	000077-92-9	Colorant		No
  4-Amino-2-hydroxytoluene	002835-95-2	Colorant		No
  Resorcinol	000108-46-3	Colorant		Yes  MN-01-Minnesota Toxic Free Kids, CHC  CoC List
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  1-Acetoxy-2-Methylnaphthalene	005697-02-9	454-690-7	Colorant	-------- ------- ---- No
  Oleamide MIPA	000111-05-7	203-828-2	Colorant	H411, H317 ------- No
  Steareth-21	009005-00-9	500-017-8	Developer	-------- ------- ---- No
  Propylene glycol	000057-55-6	200-338-0	Colorant	-------- ------- ---- No
  Oleth-10	024871-34-9	--	Colorant	-------- ------- ---- No
  Behentrimonium chloride	017301-53-0	241-327-0	Colorant	-------- ------- ---- No
  Sodium carbonate	000497-19-8	207-838-8	Colorant	H319 P264, P280, P305+P351+P338, P337+313 No
  Decyl beta-D-glucopyranoside	058846-77-8	--	Colorant	-------- ------- ---- No
  Dihydroxypropyl PEG-5 Linoleammonium chloride	168677-75-6	--	Colorant	-------- ------- ---- No
  Soytrimonium chloride	061790-41-8	263-134-0	Colorant	H302, H314, H400, H410, EUH071 ------- No
  Hydroxyethyl cellulose	009004-62-0	-	Colorant	-------- ------- ---- Yes
  1-Hydroxyethyl 4,5-diamino pyrazole sulfate	155601-30-2	429-300-3	Colorant	H317, H318, H411 P261, P273, P280, P302+P352 No
  Ascorbic Acid (Vitamin C)	000050-81-7	200-066-2	Colorant	-------- ------- ---- No
  C11-15 pareth-9	068131-40-8	614-295-4	Colorant	-------- ------- ---- No
  Dilinoleic acid	006144-28-1	--	Colorant	-------- ------- ---- No
  Fragrance(s)/perfume(s)	000000-00-1	--	Colorant	-------- ------- ---- No
  C12-15 Pareth-3	068131-39-5	500-195-7	Developer	-------- ------- ---- No
  PEG-50 hydrogenated palmamide	000000-73-6	--	Developer	-------- ------- ---- No
  Laureth-23	009002-92-0	500-002-6	Colorant	-------- ------- ---- No
  Acrylates copolymer	000000-45-9	--	Developer	-------- ------- ---- No
  Oleth-2	005274-65-7	--	Developer	-------- ------- ---- No
  Oleth-5	005353-27-5	--	Developer	-------- ------- ---- No
  Acrylates/Steareth-20 Methacrylate copolymer	000000-50-0	--	Developer	-------- ------- ---- No
  Glyceryl monostearate	031566-31-1	250-705-4	Developer	-------- ------- ---- No
  PEG-5 tallow amide	008051-63-6	--	Developer	-------- ------- ---- No
  Hydrogen peroxide	007722-84-1	231-765-0	Developer	H271, H302, H314, H332, H335, H412 ------- No
  Nonoxynol-9	026571-11-9	247-816-5	Developer	-------- ------- ---- Yes
  Isopropyl palmitate	000142-91-6	205-571-1	Developer	-------- ------- ---- No
  Cetyl alcohol	036653-82-4	253-149-0	Developer	-------- ------- ---- No
  Nonoxynol-4	007311-27-5	--	Developer	-------- ------- ---- Yes
  Ceteareth 80	068439-49-6	939-518-5	Developer	-------- ------- ---- No
  Cocamide MEA	068140-00-1	268-770-2	Colorant	-------- ------- ---- No
  PEG-80 sorbitan laurate	009005-64-5	500-018-3	Developer	-------- ------- ---- No
  Monoethanolamine (MEA)	000141-43-5	205-483-3	Colorant	H302, H312, H332, H314, H335, H412 P273, P501 No
  p-Aminophenol	000123-30-8	204-616-2	Colorant	H302, H317, H332, H341, H373, H410 P202, P261, P273, P281, P302+P352:, P304+P340, P308+P313, P501 No
  Cetostearyl alcohol	067762-27-0	267-008-6	Developer	-------- P101, P102, P280, P301+P312, P302+P352, P305+P351+P338 ---- No
  Cocoamidopropylbetaine	061789-40-0	263-058-8	Colorant	H315, H319, H317, H412 ------- No
  Olealkonium chloride	037139-99-4	253-363-4	Colorant	-------- ------- ---- No
  3-Aminophenol	000591-27-5	209-711-2	Colorant	H411, H400, H317, H302, H332 P264, P270, P301+P312, P330, P261, P271 No
  Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt)	058262-44-5	--	Colorant	-------- ------- ---- No
  p-Phenylenediamine	000106-50-3	203-404-7	Colorant	H301, H311, H331, H370, H319, H317, H410 P264, P270, P273, P311, P321, P391, P403+P233, P405, P501, P301+P310, P330, P305+P351+P338, P337+P313, P272, P302+P352, P333+P313, P363 No
  Isopropanol	000067-63-0	200-661-7	Colorant	H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No
  Diethylene glycol ethyl ether	000111-90-0	203-919-7	Colorant	-------- ------- ---- No
  Hexylene glycol	000107-41-5	203-489-0	Colorant	H315, H319 ------- No
  Nonoyl Nonoxynol-49	009014-93-1	-	Colorant	-------- ------- ---- Yes
  Oleic acid	000112-80-1	204-007-1	Colorant	-------- ------- ---- No
  Citric acid	000077-92-9	201-069-1	Colorant	H319 P264, P280, P305, P351, P338, P337, P313 No
  4-Amino-2-hydroxytoluene	002835-95-2	220-618-6	Colorant	H226, H336, H412 ------- No
  Resorcinol	000108-46-3	108-46-3	Colorant	H302, H315, H319, H400 ------- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • View Material Safety Data Sheet(MSDS)

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      December 20, 2002

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • Warnings

      Haircolor products can cause allergic reactions which in rare cases can be Severe. Tattoos may increase your risk of allergy to this product. Conduct a skin allergy test 48 hours before each time you color even if you have already used coloring products before. So remember to buy the product 48 hours in advance. Do not use the product at all if: •You have already experienced any reaction to haircolor products •You have sensitive, irritated or damaged scalp In these cases, consult a doctor before dying your hair with any haircolor product. Read and follow instructions on enclosed leaflet. In rare cases, use of hair colorants has been associated with skin depigmentation (skin lightening or loss of color). This may be temporary or permanent. If you notice any skin depigmentation or other allergic reaction such as pain or severe itching, discontinue use immediately.

    • Acute health effects

      From MSDS HEALTH HAZARDS AND HAZARD DATA FOR THE COLORANT-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide), the mixture may cause severe irritation and possible permanent eye injury. SKIN CONTACT: May cause skin irritation or sensitization in sensitized individuals. INHALATION: Inhalation of vapors may result in respiratory irritation. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HEALTH HAZARDS AND HAZARD DATA FOR THE DEVELOPER-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. SKIN CONTACT: Prolonged contact with skin may bleach it and cause burns. INHALATION: Not likely to be inhaled. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products.

    • Chronic health effects

      From MSDS HAZARD DATA FOR THE COLORANT A composite mixture of oxidative dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HAZARD DATA FOR THE DEVELOPER When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin Pre-existing dermatitis would likely be made worse by exposure to these products.

    • Carcinogenicity

      From MSDS Not listed as carcinogen by NTP, IARC or OSHA.

    • Handling information

      From MSDS COLORANT Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. DEVELOPER Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat sparks and flame. Do not store any tint, lightener, lotion or bleach powder after it has been mixed with developer; container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture.

    • Disposal information

      From MSDS Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations.

    • First Aid

      From MSDS Eye Contact: Remove contact lenses. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center.