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Clairol Natural Instincts for Men Haircolor, Brown Black-12/20/2002-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Hair DyeStructure such as solid, liquid, aerosol etc.
Form: kitDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)1-Acetoxy-2-Methylnaphthalene 005697-02-9 Colorant No 1-Hydroxyethyl 4,5-diamino pyrazole sulfate 155601-30-2 Colorant No 3-Aminophenol 000591-27-5 Colorant No 4-Amino-2-hydroxytoluene 002835-95-2 Colorant No Acetamide MEA 000142-26-7 Conditioner No Acrylates copolymer 000000-45-9 Developer No Acrylates/Steareth-20 Methacrylate copolymer 000000-50-0 Developer No Amodimethicone 071750-80-6 Conditioner No Ascorbic Acid (Vitamin C) 000050-81-7 Colorant No Behentrimonium chloride 017301-53-0 Colorant Yes CoC List
C11-15 pareth-9 068131-40-8 Colorant No C12-15 Pareth-3 068131-39-5 Developer No Ceteareth 80 068439-49-6 Developer No Cetostearyl alcohol 067762-27-0 Developer No Cetrimonium chloride 000112-02-7 Conditioner Yes CoC List
Cetyl alcohol 036653-82-4 Developer Yes CoC List
Citric acid 000077-92-9 Colorant No Cocamide MEA 068140-00-1 Colorant No Cocoamidopropylbetaine 061789-40-0 Colorant No Cyclomethicone 069430-24-6 Conditioner No Cyclopentasiloxane 000541-02-6 Conditioner Yes CoC List
Decyl beta-D-glucopyranoside 058846-77-8 Colorant No Dicetyldimonium chloride 001812-53-9 Conditioner No Diethylene glycol ethyl ether 000111-90-0 Colorant No Dihydroxypropyl PEG-5 Linoleammonium chloride 168677-75-6 Colorant No Dilinoleic acid 006144-28-1 Colorant No Dimethicone 009006-65-9 Conditioner No Disodium wheatgermamphodiacetate 000000-50-7 Conditioner No Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt) 058262-44-5 Colorant No Fragrance(s)/perfume(s) 000000-00-1 Colorant No Glycerin 000056-81-5 Conditioner No Glyceryl monostearate 031566-31-1 Conditioner No Glycol stearate 000111-60-4 Conditioner No Hexylene glycol 000107-41-5 Colorant No Hydrogen peroxide 007722-84-1 Developer Yes CoC List
Hydroxyethyl cellulose 009004-62-0 Colorant No Isopropanol 000067-63-0 Colorant Yes CoC List
Isopropyl palmitate 000142-91-6 Developer No Laureth-23 009002-92-0 Colorant No Linoleamidopropyl dimethylamine dimer dilinoleate 125804-10-6 Conditioner No Monoethanolamine (MEA) 000141-43-5 Colorant Yes CoC List
Myristyl myristate 003234-85-3 Conditioner No Nonoxynol-4 007311-27-5 Developer Yes CoC List
Nonoxynol-9 026571-11-9 Developer Yes CoC List
Nonoyl Nonoxynol-49 009014-93-1 Colorant No Olealkonium chloride 037139-99-4 Colorant No Oleamide MIPA 000111-05-7 Colorant No Oleic acid 000112-80-1 Colorant No Oleth-10 024871-34-9 Colorant No Oleth-2 005274-65-7 Developer No Oleth-5 005353-27-5 Developer No Oleyl alcohol 000143-28-2 Conditioner No p-Aminophenol 000123-30-8 Colorant No p-Phenylenediamine 000106-50-3 Colorant Yes CoC List
Paraffin oil 008012-95-1 Conditioner Yes CoC List
PEG- 100 Stearate 009004-99-3 Conditioner No PEG-5 tallow amide 008051-63-6 Developer No PEG-50 hydrogenated palmamide 000000-73-6 Developer No PEG-80 sorbitan laurate 009005-64-5 Developer No Polyquaternium-11 053633-54-8 Conditioner No Polyquaternium-7 026590-05-6 Conditioner No Propylene glycol 000057-55-6 Conditioner Yes CoC List
Quaternium-18 061789-80-8 Conditioner Yes CoC List
Resorcinol 000108-46-3 Colorant Yes CoC List
Sodium carbonate 000497-19-8 Colorant No Sodium cocoamphopropionate 068988-63-6 Conditioner No Soytrimonium chloride 061790-41-8 Colorant No Spermaceti 008002-23-1 Conditioner No Stearalkonium chloride 000122-19-0 Conditioner Yes CoC List
Stearamidopropyl diethylamine 016889-14-8 Conditioner No Steareth-21 009005-00-9 Developer No Stearyl alcohol 000112-92-5 Conditioner No Trimethylsilylamodimethicone 000000-74-5 Conditioner No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).1-Acetoxy-2-Methylnaphthalene 005697-02-9 454-690-7 Colorant -------- ------- ---- No 1-Hydroxyethyl 4,5-diamino pyrazole sulfate 155601-30-2 429-300-3 Colorant H317, H318, H411 P261, P273, P280, P302+P352 No 3-Aminophenol 000591-27-5 209-711-2 Colorant H411, H400, H317, H302, H332 P264, P270, P301+P312, P330, P261, P271 No 4-Amino-2-hydroxytoluene 002835-95-2 220-618-6 Colorant H226, H336, H412 ------- No Acetamide MEA 000142-26-7 205-530-8 Conditioner -------- ------- ---- No Acrylates copolymer 000000-45-9 -- Developer -------- ------- ---- No Acrylates/Steareth-20 Methacrylate copolymer 000000-50-0 -- Developer -------- ------- ---- No Amodimethicone 071750-80-6 - Conditioner -------- ------- ---- Yes Ascorbic Acid (Vitamin C) 000050-81-7 200-066-2 Colorant -------- ------- ---- No Behentrimonium chloride 017301-53-0 241-327-0 Colorant -------- ------- ---- No C11-15 pareth-9 068131-40-8 614-295-4 Colorant -------- ------- ---- No C12-15 Pareth-3 068131-39-5 500-195-7 Developer -------- ------- ---- No Ceteareth 80 068439-49-6 939-518-5 Developer -------- ------- ---- No Cetostearyl alcohol 067762-27-0 267-008-6 Developer -------- P101, P102, P280, P301+P312, P302+P352, P305+P351+P338 ---- No Cetrimonium chloride 000112-02-7 203-928-6 Conditioner H302, H311, H314, H410 P101, P102, P273, P280, P302+P352, P305+P351+P338, P314, P337+P313 No Cetyl alcohol 036653-82-4 253-149-0 Developer -------- ------- ---- No Citric acid 000077-92-9 201-069-1 Colorant H319 P264, P280, P305, P351, P338, P337, P313 No Cocamide MEA 068140-00-1 268-770-2 Colorant -------- ------- ---- No Cocoamidopropylbetaine 061789-40-0 263-058-8 Colorant H315, H319, H317, H412 ------- No Cyclomethicone 069430-24-6 -- Conditioner -------- ------- ---- No Cyclopentasiloxane 000541-02-6 208-764-9 Conditioner -------- ------- ---- Yes Decyl beta-D-glucopyranoside 058846-77-8 -- Colorant -------- ------- ---- No Dicetyldimonium chloride 001812-53-9 217-325-0 Conditioner -------- ------- ---- No Diethylene glycol ethyl ether 000111-90-0 203-919-7 Colorant -------- ------- ---- No Dihydroxypropyl PEG-5 Linoleammonium chloride 168677-75-6 -- Colorant -------- ------- ---- No Dilinoleic acid 006144-28-1 -- Colorant -------- ------- ---- No Dimethicone 009006-65-9 -- Conditioner -------- ------- ---- No Disodium wheatgermamphodiacetate 000000-50-7 -- Conditioner -------- ------- ---- No Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt) 058262-44-5 -- Colorant -------- ------- ---- No Fragrance(s)/perfume(s) 000000-00-1 -- Colorant -------- ------- ---- No Glycerin 000056-81-5 200-289-5 Conditioner -------- ------- ---- No Glyceryl monostearate 031566-31-1 250-705-4 Conditioner -------- ------- ---- No Glycol stearate 000111-60-4 203-886-9 Conditioner -------- ------- ---- No Hexylene glycol 000107-41-5 203-489-0 Colorant H315, H319 ------- No Hydrogen peroxide 007722-84-1 231-765-0 Developer H271, H302, H314, H332, H335, H412 ------- No Hydroxyethyl cellulose 009004-62-0 - Colorant -------- ------- ---- Yes Isopropanol 000067-63-0 200-661-7 Colorant H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No Isopropyl palmitate 000142-91-6 205-571-1 Developer -------- ------- ---- No Laureth-23 009002-92-0 500-002-6 Colorant -------- ------- ---- No Linoleamidopropyl dimethylamine dimer dilinoleate 125804-10-6 -- Conditioner -------- ------- ---- No Monoethanolamine (MEA) 000141-43-5 205-483-3 Colorant H302, H312, H332, H314, H335, H412 P273, P501 No Myristyl myristate 003234-85-3 221-787-9 Conditioner -------- ------- ---- No Nonoxynol-4 007311-27-5 -- Developer -------- ------- ---- Yes Nonoxynol-9 026571-11-9 247-816-5 Developer -------- ------- ---- Yes Nonoyl Nonoxynol-49 009014-93-1 - Colorant -------- ------- ---- Yes Olealkonium chloride 037139-99-4 253-363-4 Colorant -------- ------- ---- No Oleamide MIPA 000111-05-7 203-828-2 Colorant H411, H317 ------- No Oleic acid 000112-80-1 204-007-1 Colorant -------- ------- ---- No Oleth-10 024871-34-9 -- Colorant -------- ------- ---- No Oleth-2 005274-65-7 -- Developer -------- ------- ---- No Oleth-5 005353-27-5 -- Developer -------- ------- ---- No Oleyl alcohol 000143-28-2 205-597-3 Conditioner -------- ------- ---- No p-Aminophenol 000123-30-8 204-616-2 Colorant H302, H317, H332, H341, H373, H410 P202, P261, P273, P281, P302+P352:, P304+P340, P308+P313, P501 No p-Phenylenediamine 000106-50-3 203-404-7 Colorant H301, H311, H331, H370, H319, H317, H410 P264, P270, P273, P311, P321, P391, P403+P233, P405, P501, P301+P310, P330, P305+P351+P338, P337+P313, P272, P302+P352, P333+P313, P363 No Paraffin oil 008012-95-1 232-384-2 Conditioner -------- ------- ---- No PEG- 100 Stearate 009004-99-3 -- Conditioner -------- ------- ---- No PEG-5 tallow amide 008051-63-6 -- Developer -------- ------- ---- No PEG-50 hydrogenated palmamide 000000-73-6 -- Developer -------- ------- ---- No PEG-80 sorbitan laurate 009005-64-5 500-018-3 Developer -------- ------- ---- No Polyquaternium-11 053633-54-8 - Conditioner -------- ------- ---- Yes Polyquaternium-7 026590-05-6 - Conditioner -------- ------- ---- Yes Propylene glycol 000057-55-6 200-338-0 Conditioner -------- ------- ---- No Quaternium-18 061789-80-8 263-090-2 Conditioner -------- ------- ---- No Resorcinol 000108-46-3 108-46-3 Colorant H302, H315, H319, H400 ------- No Sodium carbonate 000497-19-8 207-838-8 Colorant H319 P264, P280, P305+P351+P338, P337+313 No Sodium cocoamphopropionate 068988-63-6 -- Conditioner -------- ------- ---- No Soytrimonium chloride 061790-41-8 263-134-0 Colorant H302, H314, H400, H410, EUH071 ------- No Spermaceti 008002-23-1 -- Conditioner -------- ------- ---- No Stearalkonium chloride 000122-19-0 204-527-9 Conditioner H302, H318, H410 P264, P270, P273, P280, P301+P312, P305+P351+P338, P310, P330, P391, P501 No Stearamidopropyl diethylamine 016889-14-8 240-924-3 Conditioner -------- ------- ---- No Steareth-21 009005-00-9 500-017-8 Developer -------- ------- ---- No Stearyl alcohol 000112-92-5 204-017-6 Conditioner -------- ------- ---- No Trimethylsilylamodimethicone 000000-74-5 -- Conditioner -------- ------- ---- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :December 20, 2002 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
Warnings
Hair color products may cause allergic reactions, which in rare instances can be serious. Do not color if you have had a previous reaction or if scalp is irritated or injured. To help minimize your risk perform the skin allergy test 48 hours before coloring. Follow enclosed instructions. Caution: This product contains ingredients which may cause skin irritation on certain individuals and a preliminary test according to accompanying instructions should first be made. This product must not be used for dyeing the eyelashes or eyebrows. To do so may cause blindness. Keep out of reach of children. -
Acute health effects
From MSDS HEALTH HAZARDS AND HAZARD DATA FOR THE COLORANT-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide), the mixture may cause severe irritation and possible permanent eye injury. SKIN CONTACT: May cause skin irritation or sensitization in sensitized individuals. INHALATION: Inhalation of vapors may result in respiratory irritation. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HEALTH HAZARDS AND HAZARD DATA FOR THE DEVELOPER-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. SKIN CONTACT: Prolonged contact with skin may bleach it and cause burns. INHALATION: Not likely to be inhaled. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. HEALTH HAZARDS AND HAZARD DATA FOR THE CONDITIONER-(MSDS 12/20/2002) The TLV of the mixture has not been established. Effects of Acute Accidental Exposure Eye Contact: Potential eye irritant. Skin Contact: Non-irritating. Inhalation: Not applicable. Ingestion: Practically non toxic. Route of Entry: Inhalation: No; Ingestion: Yes; Skin: Yes Pre-existing dermatitis would likely be made worse by exposure to these products. -
Chronic health effects
From MSDS HAZARD DATA FOR THE COLORANT A composite mixture of oxidative dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HAZARD DATA FOR THE DEVELOPER When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin Pre-existing dermatitis would likely be made worse by exposure to these products. HAZARD DATA FOR THE CONDITIONER For purposes of chronic exposure under the OSHA Hazard Communication Standard, this is an untested mixture. These products have been used extensively by consumers and Beauty Care is not aware of any significant adverse effects. Target Organs: These products contain ingredients which have been shown to affect tissues or organs when fed at high levels of exposure in animal studies not encountered in normal use. Target Organs identified in animal studies are as follows: Propylene Glycol: CNS -
Carcinogenicity
From MSDS Not listed as carcinogen by NTP, IARC or OSHA. -
Handling information
From MSDS COLORANT Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. DEVELOPER Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat sparks and flame. Do not store any tint, lightener, lotion or bleach powder after it has been mixed with developer; container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. CONDITIONER No special precautions. -
Disposal information
From MSDS Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations. -
First Aid
From MSDS Eye Contact: Remove contact lenses. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center.
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