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Clairol Hydrience Permanent Hair Color, Black Pearl, 52-12/20/2002-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Hair DyeStructure such as solid, liquid, aerosol etc.
Form: kitDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)4-Amino-2-hydroxytoluene 002835-95-2 Colorant No 3-Aminophenol 000591-27-5 Colorant No Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt) 058262-44-5 Colorant No Resorcinol 000108-46-3 Colorant Yes CoC List p-Phenylenediamine 000106-50-3 Colorant Yes CoC List Ammonium hydroxide 001336-21-6 Colorant Yes CoC List Diethylene glycol ethyl ether 000111-90-0 Colorant No Monoethanolamine (MEA) 000141-43-5 Colorant Yes CoC List Laureth-23 009002-92-0 Developer No Oleic acid 000112-80-1 Colorant No Linoleamidopropyl dimethylamine dimer dilinoleate 125804-10-6 Colorant No Cocamide MEA 068140-00-1 Colorant No Behentrimonium chloride 017301-53-0 Colorant Yes CoC List Polyquaternium-22 053694-17-0 Colorant No Dilinoleic acid 006144-28-1 Colorant No Fragrance(s)/perfume(s) 000000-00-1 Conditioner No C11-15 pareth-9 068131-40-8 Colorant No Oleamide MIPA 000111-05-7 Colorant No Cetyl alcohol 036653-82-4 Developer Yes CoC List Oleyl alcohol 000143-28-2 Colorant No C12-15 Pareth-3 068131-39-5 Developer No Propylene glycol 000057-55-6 Colorant Yes CoC List Soytrimonium chloride 061790-41-8 Colorant No Steareth-21 009005-00-9 Developer No Oleth-10 024871-34-9 Colorant No Sodium sulfate decahydrate 007727-73-3 Colorant No Caramel 008028-89-5 Colorant No Water 007732-18-5 Conditioner No Amodimethicone 071750-80-6 Conditioner No Stearyl alcohol 000112-92-5 Conditioner No Stearamidopropyl dimethylamine 007651-02-7 Conditioner No Dicetyldimonium chloride 001812-53-9 Conditioner No Glutamic Acid 000056-86-0 Conditioner No Benzyl alcohol 000100-51-6 Conditioner Yes CoC List EDTA tetrapotassium salt 005964-35-2 Conditioner No Trimethylsiloxysilicate 056275-01-5 Conditioner No Safflower seed oil 008001-23-8 Conditioner No Tocopheryl acetate 007695-91-2 Conditioner No Vegetable protein, hydrolyzed 100209-45-8 Conditioner No Panthenol 000081-13-0 Conditioner No Camellia Oleifera Leaf Extract 094333-93-4 Conditioner No Clover extract 977002-83-7 Conditioner No Verbena officinalis extract 084961-67-1 Conditioner No Methylchloroisothiazoline 026172-55-4 Conditioner No Methylisothiazoline 002682-20-4 Conditioner No FD&C (or D&C) Yellow #5 (C.I. 19140) 001934-21-0 Conditioner No Aloe Barbadensis leaf juice 094349-62-9 Conditioner No D&C Green #3 002353-45-9 Conditioner No Nonoxynol-4 007311-27-5 Developer Yes CoC List Isopropyl palmitate 000142-91-6 Developer No Nonoxynol-9 026571-11-9 Developer Yes CoC List Hydrogen peroxide 007722-84-1 Developer Yes CoC List PEG-5 tallow amide 008051-63-6 Developer No Glyceryl monostearate 031566-31-1 Developer No Cetostearyl alcohol 067762-27-0 Developer No PEG-50 hydrogenated palmamide 000000-73-6 Developer No Oleth-5 005353-27-5 Developer No Oleth-2 005274-65-7 Developer No Acrylates copolymer 000000-45-9 Developer No PEG-80 sorbitan laurate 009005-64-5 Developer No Acrylates/Steareth-20 Methacrylate copolymer 000000-50-0 Developer No Ceteareth 80 068439-49-6 Developer No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).4-Amino-2-hydroxytoluene 002835-95-2 220-618-6 Colorant H226, H336, H412 ------- No 3-Aminophenol 000591-27-5 209-711-2 Colorant H411, H400, H317, H302, H332 P264, P270, P301+P312, P330, P261, P271 No Ethanol, 2,2'-((4-aminophenyl)imino)bis-, sulfate (salt) 058262-44-5 -- Colorant -------- ------- ---- No Resorcinol 000108-46-3 108-46-3 Colorant H302, H315, H319, H400 ------- No p-Phenylenediamine 000106-50-3 203-404-7 Colorant H301, H311, H331, H370, H319, H317, H410 P264, P270, P273, P311, P321, P391, P403+P233, P405, P501, P301+P310, P330, P305+P351+P338, P337+P313, P272, P302+P352, P333+P313, P363 No Ammonium hydroxide 001336-21-6 215-647-6 Colorant H314, H335, H400 P260, P280, P301+P330+P331, P305+P351+P338, P391, P501 No Diethylene glycol ethyl ether 000111-90-0 203-919-7 Colorant -------- ------- ---- No Monoethanolamine (MEA) 000141-43-5 205-483-3 Colorant H302, H312, H332, H314, H335, H412 P273, P501 No Laureth-23 009002-92-0 500-002-6 Developer -------- ------- ---- No Oleic acid 000112-80-1 204-007-1 Colorant -------- ------- ---- No Linoleamidopropyl dimethylamine dimer dilinoleate 125804-10-6 -- Colorant -------- ------- ---- No Cocamide MEA 068140-00-1 268-770-2 Colorant -------- ------- ---- No Behentrimonium chloride 017301-53-0 241-327-0 Colorant -------- ------- ---- No Polyquaternium-22 053694-17-0 - Colorant -------- ------- ---- Yes Dilinoleic acid 006144-28-1 -- Colorant -------- ------- ---- No Fragrance(s)/perfume(s) 000000-00-1 -- Conditioner -------- ------- ---- No C11-15 pareth-9 068131-40-8 614-295-4 Colorant -------- ------- ---- No Oleamide MIPA 000111-05-7 203-828-2 Colorant H411, H317 ------- No Cetyl alcohol 036653-82-4 253-149-0 Developer -------- ------- ---- No Oleyl alcohol 000143-28-2 205-597-3 Colorant -------- ------- ---- No C12-15 Pareth-3 068131-39-5 500-195-7 Developer -------- ------- ---- No Propylene glycol 000057-55-6 200-338-0 Colorant -------- ------- ---- No Soytrimonium chloride 061790-41-8 263-134-0 Colorant H302, H314, H400, H410, EUH071 ------- No Steareth-21 009005-00-9 500-017-8 Developer -------- ------- ---- No Oleth-10 024871-34-9 -- Colorant -------- ------- ---- No Sodium sulfate decahydrate 007727-73-3 -- Colorant -------- ------- ---- No Caramel 008028-89-5 232-435-9 Colorant -------- ------- ---- No Water 007732-18-5 231-791-2 Conditioner -------- ------- ---- No Amodimethicone 071750-80-6 - Conditioner -------- ------- ---- Yes Stearyl alcohol 000112-92-5 204-017-6 Conditioner -------- ------- ---- No Stearamidopropyl dimethylamine 007651-02-7 231-609-1 Conditioner H318, H400, H411 P280, P305+P351+P338, P310, P273, P391, P501 No Dicetyldimonium chloride 001812-53-9 217-325-0 Conditioner -------- ------- ---- No Glutamic Acid 000056-86-0 200-293-7 Conditioner -------- ------- ---- No Benzyl alcohol 000100-51-6 202-859-9 Conditioner H302, H332 ------- No EDTA tetrapotassium salt 005964-35-2 227-743-5 Conditioner H373, H302, H318, H332 P261, P264, P280, P305+P351+P338, P310 No Trimethylsiloxysilicate 056275-01-5 -- Conditioner -------- ------- ---- No Safflower seed oil 008001-23-8 232-276-5 Conditioner -------- ------- ---- No Tocopheryl acetate 007695-91-2 231-710-0 Conditioner -------- ------- ---- No Vegetable protein, hydrolyzed 100209-45-8 309-353-8 Conditioner -------- ------- ---- No Panthenol 000081-13-0 201-327-3 Conditioner -------- ------- ---- No Camellia Oleifera Leaf Extract 094333-93-4 305-073-5 Conditioner -------- ------- ---- No Clover extract 977002-83-7 -- Conditioner -------- ------- ---- No Verbena officinalis extract 084961-67-1 284-657-0 Conditioner -------- ------- ---- No Methylchloroisothiazoline 026172-55-4 247-500-7 Conditioner -------- ------- ---- No Methylisothiazoline 002682-20-4 220-239-6 Conditioner H301, H311, H314, H330, H317, H410, EUH071 ------- No FD&C (or D&C) Yellow #5 (C.I. 19140) 001934-21-0 217-699-5 Conditioner -------- ------- ---- No Aloe Barbadensis leaf juice 094349-62-9 305-181-2 Conditioner -------- ------- ---- No D&C Green #3 002353-45-9 219-091-5 Conditioner -------- ------- ---- No Nonoxynol-4 007311-27-5 -- Developer -------- ------- ---- Yes Isopropyl palmitate 000142-91-6 205-571-1 Developer -------- ------- ---- No Nonoxynol-9 026571-11-9 247-816-5 Developer -------- ------- ---- Yes Hydrogen peroxide 007722-84-1 231-765-0 Developer H271, H302, H314, H332, H335, H412 ------- No PEG-5 tallow amide 008051-63-6 -- Developer -------- ------- ---- No Glyceryl monostearate 031566-31-1 250-705-4 Developer -------- ------- ---- No Cetostearyl alcohol 067762-27-0 267-008-6 Developer -------- P101, P102, P280, P301+P312, P302+P352, P305+P351+P338 ---- No PEG-50 hydrogenated palmamide 000000-73-6 -- Developer -------- ------- ---- No Oleth-5 005353-27-5 -- Developer -------- ------- ---- No Oleth-2 005274-65-7 -- Developer -------- ------- ---- No Acrylates copolymer 000000-45-9 -- Developer -------- ------- ---- No PEG-80 sorbitan laurate 009005-64-5 500-018-3 Developer -------- ------- ---- No Acrylates/Steareth-20 Methacrylate copolymer 000000-50-0 -- Developer -------- ------- ---- No Ceteareth 80 068439-49-6 939-518-5 Developer -------- ------- ---- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :December 20, 2002 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
Warnings
Hair color products may cause allergic reactions, which in rare instances can be serious. Tattoos may increase your risk of allergy to this product. Do not color if you have had a previous reaction or if scalp is irritated or injured. To help minimize your risk perform the skin allergy test 48 hours before coloring. Do not use product at all if: you have already experience any reaction to hair color products and/or you have sensitive, irritated or damaged scalp. In these cases, consult a doctor before dyeing your hair with any hair product. Read and Follow Enclosed Instructions on leaflet. In rare cases, use of this hair colorants have been associated with skin depigmentation (skin lighting or loss of color). This may be temporary or permanent. If you notice any skin depigmentation or other allergic reaction such as pain or severe itching, discontinue use immediately. This product contains ingredients which may cause skin irritation on certain individuals and a preliminary test according to accompanying instructions should first be made. This product must not be used for dyeing the eyelashes or eyebrows. To do so may cause blindness. Product not intended to be used on children keep out of reach of children. -
Acute health effects
From MSDS HEALTH HAZARDS AND HAZARD DATA FOR THE COLORANT-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide), the mixture may cause severe irritation and possible permanent eye injury. SKIN CONTACT: May cause skin irritation or sensitization in sensitized individuals. INHALATION: Inhalation of ammonia vapors may result in respiratory irritation. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: Yes; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HEALTH HAZARDS AND HAZARD DATA FOR THE DEVELOPER-(MSDS 12/20/2002) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. SKIN CONTACT: Prolonged contact with skin may bleach it and cause burns. INHALATION: Not likely to be inhaled. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. HEALTH HAZARDS AND HAZARD DATA FOR THE CONDITIONER-(MSDS 9/3/04) Avoid eye contact. May cause slight eye irritation and discomfort. If eye contact occurs, flush with water. Avoid prolonged skin contact. May cause mild irritation. Flush with water. Signs of Symptoms of Exposure: May cause nausea if ingested. If prolonged contact occurs, redness of the skin may occur. -
Chronic health effects
From MSDS HAZARD DATA FOR THE COLORANT A composite mixture of oxidative dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HAZARD DATA FOR THE DEVELOPER When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin Pre-existing dermatitis would likely be made worse by exposure to these products. HAZARD DATA FOR THE CONDITIONER Avoid prolonged skin contact. -
Carcinogenicity
From MSDS Not listed as carcinogen by NTP, IARC or OSHA. -
Handling information
From MSDS COLORANT Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. DEVELOPER Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat sparks and flame. Do not store any tint, lightener, lotion or bleach powder after it has been mixed with developer; container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. CONDITIONER No special precautions. -
Disposal information
From MSDS Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations. -
First Aid
From MSDS Eye Contact: Remove contact lenses. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center.
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