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CPID

Health effects of consumer products

Ortho Roach, Ant & Spider Killer-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Esfenvalerate	066230-04-4	0.05		Yes  NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Prallethrin	023031-36-9	0.03		Yes  NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals  CoC List
  N-Octyl bicycloheptene dicarboximide (MGK 264)	000113-48-4	0.3		No
  Petroleum distillate(s) (unspecified)	000000-02-6	99.62		No
  Water	007732-18-5	--		No
  MSDS: Proprietary or trade secret ingredient(s)	000000-00-8	--		No
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Esfenvalerate	066230-04-4	-	0.05	H331, H301, H317, H400, H410 ------- Yes
  Prallethrin	023031-36-9	245-387-9	0.03	H331, H302, H400, H410 ------- No
  N-Octyl bicycloheptene dicarboximide (MGK 264)	000113-48-4	204-029-1	0.3	H332, H411, H317 P261, P271, P280, P273, P304+P340, P391, P501 No
  Petroleum distillate(s) (unspecified)	000000-02-6	--	99.62	-------- ------- ---- No
  Water	007732-18-5	231-791-2	--	-------- ------- ---- No
  MSDS: Proprietary or trade secret ingredient(s)	000000-00-8	--	--	-------- ------- ---- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      August 29, 2000

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	1	1	1

    • Warnings

      MAY BE HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH THE SKIN CAUSES MILD EYE IRRITATION AND MODERATE SKIN IRRITATION REPEATED DERMAL EXPOSURE MAY CAUSE SKIN SENSITIZATION REACTION AVOID BREATHING VAPOR OR SPRAY MIST AVOID CONTACT WITH EYES, SKIN, OR CLOTHING KEEP OUT OF REACH OF CHILDREN.

    • Acute health effects

      From MSDS POTENTIAL HEALTH EFFECTS EYES: This product may be mildly irritating to the eyes. Eye irritation may include; discomfort, redness, swelling and blurred vision. SKIN: This product is a moderate dermal irritant and repeated skin contact may cause an allergic skin reaction in some individuals. INGESTION: If swallowed, this product may cause gastrointestinal tract irritation. INHALATION: Overexposure to the spray mist may be irritating to the respiratory tract. If inhaled, this substance is considered practically non-toxic to internal organs. COMMENTS HEALTH: This product contains esfenvalerate, a cyano-pyrethroid that has the potential to cause temporary dermal paresthesia, e.g. burning, tingling, stinging sensations, that may occur following overexposure. However, using spray dilutions as indicated on the product label, it is unlikely that skin exposure to the spray mist will deliver sufficient concentrations of the active ingredient to trigger the dermal symptoms.

    • Chronic health effects

      From MSDS GENERAL COMMENTS: Paresthesias: Esfenvalerate is a cyano-pyrethroid insecticide that has been associated with skin paresthesia in cases of extensive overexposure. The paresthesia symptoms are transient and consistent of tingling, burning, stinging sensations at the site of contact. The intensity of the sensory effect depends upon the extent of overexposure, individual skin sensitivity and environmental factors, e.g. hot, cold, pressure, etc. Clinically, the cutaneous sensations may be delayed a few hours, peak around 8-12 hours and remit within a few days. The sensations are usually not accompanied by a visible irritation or rash. TERATOGENICITY: Esfenvalerate is not considered to be a teratogen. Results of the rat and rabbit teratology investigations indicated that the NOEL's for maternal and developmental toxicity in both species were 2.0 and 20 mg/kg/dy (highest dose tested), respectively. REPRODUCTIVE TOXIN: Results of the esfenvalerate 2-generation reproduction study demonstrated that the chemical was not associated with any adverse reproduction effects. The NOEL was 3.75 mg/kg/dy. MUTAGENICITY: Based on the results of both in vivo and in vitro mutagenesis testing, esfenvalerate is not considered to be a mutagen.

    • Carcinogenicity

      From MSDS CARCINOGENICITY COMMENTS: Results of rat and mouse lifetime feeding studies did not demonstrate any evidence that fenvalerate (esfenvalerate major isomer) was associated with carcinogenic activity. The results of the rat and mouse chronic feeding studies indicated the NOELs (no observable effect levels) were 12.5 and 15 mg/kg/day, respectively. Based on the results of the investigations, EPA has classed fenvalerate in carcinogenicity class E (no evidence of carcinogenicity in either rats or mice). In addition, the chemical is not considered to be a carcinogen by IARC, NTP, OSHA or ACGIH.

    • Handling information

      From MSDS GENERAL PROCEDURES: READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. DO NOT USE OR STORE near flame, sparks or hot surfaces. USE ONLY IN WELL VENTILATED AREA. Exposure to heat or prolonged exposure to sun may cause container to burst. Do not puncture, incinerate, or store above 120 F. Do not apply directly to water or wetlands. Do not contaminate water by cleaning of equipment or disposal of waste. For help with any spill, leak, fire or exposure involving this material, call day or night (800) 454-2333. ECOTOXICOLOGICAL INFORMATION: This material is highly toxic to fish. Do not apply directly to water. Drift from treated area may be hazardous to organisms in adjacent aquatic sites. Do not pour product or rinse water down any drain. This pesticide is classed as very low to slightly toxic to birds and highly toxic to bees by direct contact. Once foliar residue has dried, the hazard is insignificant.

    • Disposal information

      From MSDS DISPOSAL METHOD: Unused product may be disposed of by replacing cap, securely wrapping original container in several layers of newspaper and discarding in trash. Do not incinerate or puncture.

    • First Aid

      From MSDS EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice. SKIN: If on skin or clothing, take of contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice. INGESTION: If swallowed, call a poison control center or doctor immediately for treatment advice. Have person sip glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never give anything by mouth to an unconscious person. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.