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Prestone Ice + Frost Shield Windshield Glass Treatment-09/17/2019
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: DeicerStructure such as solid, liquid, aerosol etc.
Form: pump sprayDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 20, 202369 Eagle Road
Danbury CT 06810
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Methanol 000067-56-1 200-659-6 40.0-70.0 H225, H331, H311, H301, H370 ------- No Ethylene glycol 000107-21-1 203-473-3 0-40.0 H302, H373 ------- No Propylene glycol 000057-55-6 200-338-0 0-40.0 -------- ------- ---- No Diethylene glycol 000111-46-6 203-872-2 0-5.0 H302 ------- No Silane (unspecified) 888888-07-0 -- 0-1.5 -------- ------- ---- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :September 17, 2019 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3 2 0 -
Warnings
Hazard Statements
Danger. Contains Methyl Alcohol (Methanol). Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes damage to eyes and central nervous system. May cause damage to kidneys through prolonged or repeated exposure.
Precautionary Statements
General
None.
Prevention
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground or Bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting, and equipment. Use only non-sparking tools. Take action to prevent static discharge. Do not breathe mist or vapors. Wash exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves, protective clothing, and eye protection.
Response
IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Call a POISON CENTER or doctor if you feel unwell. Wash contaminated clothing before reuse.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor.
In case of fire: Use water fog, carbon dioxide, alcohol foam or dry chemical to extinguish.
Storage
Store in a well-ventilated place. Keep cool. Store locked up.
Disposal
Dispose of contents and container in accordance with local and national regulations. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Danger. Contains Methyl Alcohol (Methanol). Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes damage to eyes and central nervous system. May cause damage to kidneys through prolonged or repeated exposure.
Potential Health Effects
Eye contact: Liquid, vapors or mist may cause discomfort in the eye with persistent conjunctivitis, seen as slight excess redness or conjunctiva. Serious corneal injury is not anticipated.
Skin Contact: Prolonged contact with the skin may cause redness and defatting of the skin and absorption of harmful amounts of methanol.
Inhalation: May cause irritation of the nose and throat. High vapor concentrations may produce nausea, vomiting, headache, dizziness, drowsiness, tingling, numbness and shooting pains in the hands and forearms, and visual disturbances.
Ingestion: Contains methanol and ethylene glycol. May cause abdominal discomfort or pain, nausea, vomiting, dizziness, drowsiness, headache, malaise, blurring of vision, irritability, back pain, decrease in urine output, kidney failure, and central nervous system effects, including irregular eye movements, convulsions and coma. Visual effects from methanol include blurred vision, double vision, changes in color perception, restriction of visual fields and complete blindness. Cardiac failure and pulmonary edema may develop. Severe kidney damage which may be fatal follows the swallowing of large volumes of ethylene glycol. Signs of renal insufficiency may be delayed 36 to 48 hours post ingestion. A few reports have been published describing the development of weakness of the facial muscles, diminishing hearing, and difficulty with swallowing, during the late stages of severe poisoning. With massive overdoses of methanol, liver, kidney and heart muscle injury have been described. There may be a delay of 6-12 hours between swallowing methanol and the onset of signs and symptoms. Ingestion of moderate quantities of methanol also produces metabolic acidosis. 60-200 ml of methanol is a fatal dose for most adults. Ingestion of as little as 10 ml may cause blindness. -
Chronic health effects
From SDS:
Prolonged or repeated inhalation exposure may produce signs of central nervous system involvement, including nausea, vomiting, headache, ringing in the ears, dizziness, vertigo, cloudy and double vision. Prolonged overexposure at levels of 800-1000 ppm may result and in severe eye damage. Prolonged or repeated skin contact may cause skin sensitization and an associated dermatitis in some individuals. Ethylene glycol has been found to cause birth defects in laboratory animals. The significance of this finding to humans has not been determined. -
Carcinogenicity
None of the components of these products is listed as a carcinogen or suspected carcinogenby IARC, NTP, ACGIH or OSHA. -
Handling information
Flammable liquid! May be fatal or cause blindness if swallowed! Do not swallow. Do not eat, drink or smoke when using this product. Do not breathe mists or vapors. Use only outdoors or in a well-ventilated area. Avoid eye and skin contact. Wash exposed skin thoroughly after handling. Wear appropriate protective clothing and equipment. Take off immediately all contaminated clothing. Wash contaminated clothing before reuse.Keep away from heat, sparks, open flames and all other sources of ignition. Keep container tightly closed. Store locked up in a cool, well ventilated area away from oxidizers. -
Disposal information
Dispose of product as hazardous waste (ignitable) in accordance with all local, state/provincial and federal regulations. -
California Prop. 65 Warning
This product contains the following chemicals regulated under California Proposition 65:
Methanol CAS No. 000067-56-1, developmental
Ethylene Glycol CAS No. 000107-21-1, developmental -
First Aid
Eye Contact: Immediately flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists.Skin Contact: Remove contaminated clothing. Immediately wash contacted area thoroughly with soap and water. If irritation persists, get medical attention.Inhalation: Remove the victim to fresh air. If breathing has stopped administer artificial respiration. If breathing is difficult, have medical personnel administer oxygen. Get immediate medical attention.Ingestion: Seek immediate medical attention. Immediately call local poison control center or go to an emergency department. Never give anything by mouth to or induce vomiting in an unconscious or drowsy person.Notes to Physician: The combination of visual disturbances, metabolic acidosis and an osmol gap is evidence of methanol poisoning. Ethanol is antidotal and its early administration may block the formation of toxic metabolites of methanol. The principal toxic effect of ethylene glycol, when swallowed, are kidney damage and metabolic acidosis. The combination of metabolic acidosis, an osmol gap and oxalate crystals in the urine is evidence of ethylene glycol poisoning. Ethanol is antidotal and its early administration may block the formation of nephrotoxic metabolites of ethylene glycol in the liver. The objective is to rapidly achieve and maintain a blood ethanol level of approximately 100 mg/dl by giving a loading dose of ethanol followed by a maintenance dose. Intravenous administration of ethanol is the preferred route. Ethanol blood levels should be checked frequently. Hemodialysismay be required. 4-Methyl pyrazole (Fomepizole(R)), a potent inhibitor of alcohol dehydrogenase, has been used therapeutically to decrease the metabolic consequences of methanol and ethylene glycol poisoning. This antidote is now approved by the F.D.A. and in many cases has replaced ethanol in the treatment of ethylene glycol poisoning. Pulmonary edema with hypoxia has been described in a number of patients following poisoning with ethylene glycol. Respiratory support with mechanical ventilation may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and dysphagia. As there are complicated and serious overdoses, we recommend you consult with the toxicologists at your poison control center.
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