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Clairol Hydrience Permanent Hair Color, Black Pearl, 52-Old Product
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Hair DyeStructure such as solid, liquid, aerosol etc.
Form: kitDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 14, 2024P.O. Box 599
Cincinnati OH 45201
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 000081-13-0 -- Conditioner -- -- -- -- 068439-49-6 -- Developer -- -- -- -- 026161-33-1 -- Developer -- -- -- -- 000667-83-4 -- Conditioner -- -- -- -- 007651-02-7 -- Conditioner -- -- -- -- 012001-26-2 -- Colorant -- -- -- -- 007732-18-5 -- Colorant -- -- -- -- 068140-00-1 -- Colorant -- -- -- -- 006144-28-1 -- Colorant -- -- -- -- 009062-04-8 -- Developer -- -- -- -- 024938-91-8 -- Developer -- -- -- -- 000000-00-1 -- Colorant -- -- -- -- 000000-00-1 -- Colorant -- -- -- -- 009002-92-0 -- Developer -- -- -- -- 001260-17-9 -- Colorant -- -- -- -- 999999-60-2 -- Colorant -- -- -- -- 063886-75-9 -- Colorant -- -- -- -- 013463-67-7 -- Colorant -- -- -- -- 006834-92-0 -- Colorant Xi, C -- -- -- -- 000060-00-4 -- Colorant Xi -- -- -- -- 068917-51-1 -- Colorant -- -- -- -- 001336-21-6 -- Colorant C, N, Xi -- -- -- -- 009005-00-9 -- Colorant -- -- -- -- 000100-51-6 -- Conditioner Xn -- -- -- -- 000056-86-0 -- Conditioner -- -- -- -- 036653-82-4 -- Conditioner -- -- -- -- 000112-92-5 -- Conditioner -- -- -- -- 026172-55-4 -- Conditioner -- -- -- -- 000060-00-4 -- Colorant Xi -- -- -- -- 007722-84-1 -- Developer O, C, Xn -- -- -- -- 007732-18-5 -- Colorant -- -- -- -- 024871-34-9 -- Colorant -- -- -- -- 025086-29-7 -- Developer -- -- -- -- 009005-00-9 -- Colorant -- -- -- -- 067762-27-0 -- Developer -- -- -- -- 002809-21-4 -- Developer -- -- -- -- 006166-86-5 -- Conditioner -- -- -- -- 007732-18-5 -- Developer -- -- -- -- 009006-65-9 -- Conditioner -- -- -- -- 000106-50-3 -- Colorant -- -- -- -- 068131-39-5 -- Colorant -- -- -- -- 125804-10-6 -- Colorant -- -- -- -- 017301-53-0 -- Colorant -- -- -- -- 000089-65-6 -- Colorant -- -- -- -- 007757-83-7 -- Colorant -- -- -- -- 000108-46-3 -- Colorant Xn, Xi, N -- -- -- -- 000591-27-5 -- Colorant Xn, N -- -- -- -- 000050-70-4 -- Colorant -- -- -- -- 002682-20-4 -- Conditioner -- -- -- -- 053694-17-0 -- Colorant -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Panthenol
000081-13-0
201-327-3Conditioner No -- -- -- No No Ceteareth 80
068439-49-6
939-518-5Developer No -- -- -- No No Polyquaternium-37
026161-33-1
-Developer No -- -- -- Yes No Panthenyl ethyl ether
000667-83-4
211-569-1Conditioner No -- -- -- No No Stearamidopropyl dimethylamine
007651-02-7
231-609-1Conditioner No H318, H400, H411 P280, P305+P351+P338, P310, P273, P391, P501 No No Mica
012001-26-2
-Colorant No -- -- -- Yes No Water
007732-18-5
231-791-2Colorant No -- -- -- No No Cocamide MEA
068140-00-1
268-770-2Colorant No -- -- -- No No Dilinoleic acid
006144-28-1
--Colorant No -- -- -- No No Propylene glycol dicaprylate/dicaprate
009062-04-8
--Developer No -- -- -- No No Trideceth-12
024938-91-8
-Developer No -- -- -- Yes No Fragrance(s)/perfume(s)
000000-00-1
--Colorant No -- -- -- No No Fragrance(s)/perfume(s)
000000-00-1
--Colorant No -- -- -- No No Laureth-23
009002-92-0
500-002-6Developer No -- -- -- No No Carmine
001260-17-9
215-023-3Colorant No -- -- -- No No Iron oxide(s) (unspecified)
999999-60-2
--Colorant No -- -- -- No No N,N-bis(2-Hydroxyethyl)-p-phenylenediamine sulfate
063886-75-9
--Colorant No -- -- -- No No Titanium dioxide
013463-67-7
236-675-5Colorant No -- -- -- No No Sodium metasilicate
006834-92-0
229-912-9Colorant No H290, H314, H335 P261, P262, P280, P301+P330+P331, P303+P361+P353, P305+P351+P338 No No Ethylenediaminetetraacetic acid (EDTA)
000060-00-4
200-449-4Colorant No H319 -- No No Fucus Vesiculous Extract
068917-51-1
295-780-4Colorant No -- -- -- No No Ammonium hydroxide
001336-21-6
215-647-6Colorant No H314, H335, H400 P260, P280, P301+P330+P331, P305+P351+P338, P391, P501 No No Steareth-21
009005-00-9
500-017-8Colorant No -- -- -- No No Benzyl alcohol
000100-51-6
202-859-9Conditioner No H302, H332 -- No No Glutamic Acid
000056-86-0
200-293-7Conditioner No -- -- -- No No Cetyl alcohol
036653-82-4
253-149-0Conditioner No -- -- -- No No Stearyl alcohol
000112-92-5
204-017-6Conditioner No -- -- -- No No Methylchloroisothiazoline
026172-55-4
247-500-7Conditioner No -- -- -- No No Ethylenediaminetetraacetic acid (EDTA)
000060-00-4
200-449-4Colorant No H319 -- No No Hydrogen peroxide
007722-84-1
231-765-0Developer No H271, H302, H314, H332, H335, H412 -- No No Water
007732-18-5
231-791-2Colorant No -- -- -- No No Oleth-10
024871-34-9
--Colorant No -- -- -- No No Styrene/PVP copolymer
025086-29-7
--Developer No -- -- -- No No Steareth-21
009005-00-9
500-017-8Colorant No -- -- -- No No Cetostearyl alcohol
067762-27-0
267-008-6Developer No -- P101, P102, P280, P301+P312, P302+P352, P305+P351+P338 -- No No Etidronic acid
002809-21-4
220-552-8Developer No H290, H318, H302 P234, P390, P406, P280, P305+P351+P338, P310, P264, P270, P301+P312, P330, P501 No No Cyclopentasiloxane, 2,4,6,8,10-pentamethyl-
006166-86-5
228-204-7Conditioner No H226 P210, P243, P403+P235 No No Water
007732-18-5
231-791-2Developer No -- -- -- No No Dimethicone
009006-65-9
--Conditioner No -- -- -- No No p-Phenylenediamine
000106-50-3
203-404-7Colorant No H301, H311, H331, H370, H319, H317, H410 P264, P270, P273, P311, P321, P391, P403+P233, P405, P501, P301+P310, P330, P305+P351+P338, P337+P313, P272, P302+P352, P333+P313, P363 No No C12-15 Pareth-3
068131-39-5
500-195-7Colorant No -- -- -- No No Linoleamidopropyl dimethylamine dimer dilinoleate
125804-10-6
--Colorant No -- -- -- No No Behentrimonium chloride
017301-53-0
241-327-0Colorant No -- -- -- No No Isoascorbic acid
000089-65-6
201-928-0Colorant No -- -- -- No No Sodium sulfite
007757-83-7
231-821-4Colorant No -- -- -- No No Resorcinol
000108-46-3
108-46-3Colorant No H302, H315, H319, H400 -- No No 3-Aminophenol
000591-27-5
209-711-2Colorant No H411, H400, H317, H302, H332 P264, P270, P301+P312, P330, P261, P271 No No Sorbitol
000050-70-4
200-061-5Colorant No -- -- -- No No Methylisothiazoline
002682-20-4
220-239-6Conditioner No H301, H311, H314, H330, H317, H410, EUH071 -- No No Polyquaternium-22
053694-17-0
-Colorant No -- -- -- Yes No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H226 : Flammable liquid and vapourH271 : May cause fire or explosion; strong oxidizerH290 : May be corrosive to metalsH301 : Toxic if swallowedH302 : Harmful if swallowedH311 : Toxic in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH317 : May cause an allergic skin reactionH318 : Causes serious eye damageH319 : Causes serious eye irritationH330 : Fatal if inhaledH331 : Toxic if inhaledH332 : Harmful if inhaledH335 : May cause respiratory irritationH370 : Causes damage to organsH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effectsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effectsEUH071 : Corrosive to the respiratory tract
- P101 : If medical advice is needed, have product container or label at handP102 : Keep out of reach of childrenP210 : Keep away from heat/sparks/open flames/hot surfacesP234 : Keep only in original containerP243 : Take precautionary measures against static dischargeP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP262 : Do not get in eyes, on skin, or on clothingP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP271 : Use only outdoors or in a well-ventilated areaP272 : Contaminated work clothing should not be allowed out of the workplaceP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP310 : Immediately call a POISON CENTER or doctor/physicianP311 : Call a POISON CENTER or doctor/physicianP321 : Specific treatment (see … on this label)P330 : Rinse mouthP363 : Wash contaminated clothing before reuseP390 : Absorb spillage to prevent material-damageP391 : Collect spillageP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP301+P330+P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomitingP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP333+P313 : If skin irritation or a rash occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP405 : Store locked upP406 : Store in a corrosive resistant/… container with a resistant inner linerP501 : Dispose of contents/container to
- GHS03 : OxidiserGHS05 : CorrosiveGHS06 : ToxicGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :February 14, 2002 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATINGN N N -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
This product contains ingredients that may cause skin irritation on certain individuals, and a preliminary test according to accompanying directions should first be made. This product must not be used for dyeing the eyelashes or eyebrows; to do so may cause blindness. -
Acute health effects
From MSDS HEALTH HAZARDS AND HAZARD DATA FOR THE COLORANT-(MSDS 2/14/02) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide), the mixture may cause severe irritation and possible permanent eye injury. SKIN CONTACT: May cause skin irritation or sensitization in sensitive individuals. INHALATION: Inhalation of ammonia vapors may result in respiratory irritation. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: Yes; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HEALTH HAZARDS AND HAZARD DATA FOR THE DEVELOPER-(MSDS 9/4/01) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. SKIN CONTACT: Prolonged contact with skin may bleach it and cause burns. INHALATION: Not likely to be inhaled. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. HEALTH HAZARDS AND HAZARD DATA FOR THE CONDITIONER-(MSDS 9/4/01) The TLV of the mixture has not been established. EYE CONTACT: Potential eye irritant. SKIN CONTACT: Potential skin irritant. INHALATION: Not applicable. INGESTION: Practically non toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. -
Chronic health effects
From MSDS HAZARD DATA FOR THE COLORANT A composite mixture of oxidative dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HAZARD DATA FOR THE DEVELOPER When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin Pre-existing dermatitis would likely be made worse by exposure to these products. HAZARD DATA FOR THE CONDITIONER For purposes of chronic exposure under the OSHA Hazard Communication Standard, this is an untested mixture. These products have been used extensively by consumers and Worldwide Beauty Care is not aware of any significant adverse effects. Target Organs: These products contain ingredients which have been shown to affect tissues or organs when fed at high levels of exposure in animal studies not encountered in normal use. Target Organs identified in animal studies are as follows: Glycerin:- Kidney, Liver; Propylene Glycol:- CNS; Isopropyl Alcohol:- CNS. Pre-existing dermatitis would likely be made worse by exposure to these products. -
Carcinogenicity
From MSDS Not listed as carcinogen by NTP, IARC or OSHA. -
Handling information
From MSDS COLORANT Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. DEVELOPER Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat sparks and flame. Do not store any tint, lightener, lotion or bleach powder after it has been mixed with developer; container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. CONDITIONER No precautions necessary. -
Disposal information
From MSDS Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations. -
First Aid
From MSDS Eye Contact: Remove contact lenses, if used. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center.
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