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CPID

Health effects of consumer products

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned ID numbers (with 6 leading zeros or nines, e.g., 000000-xx-x or 999999-xx-x) for blends and chemicals that do not have CAS numbers.

  CAS No./ID

  Percent of chemical in preparation.

  % Conc.

  Butoxytriglycol	000143-22-6	20.0-75.0
  Methoxytriglycol	000112-35-6	0-30.0
  Ethoxytriglycol	000112-50-5	0-40.0
  Tetraethylene glycol, monobutyl ether	001559-34-8	0-15.0
  Diethylene glycol monobutyl ether	000112-34-5	1-30.0
  Diethylene glycol ethyl ether	000111-90-0	0-2.0
  Tetraethylene glycol	000112-60-7	0-20.0
  Diethylene glycol	000111-46-6	0-60.0
  Triethylene glycol	000112-27-6	0-20.0
  Glycols, polyethylene	025322-68-3	0-20.0
  PEG-6 methyl ether	009004-74-4	0-20.0
  Polyethylene glycol, monobutyl ester	009004-77-7	0-20.0
  Polyethylene glycol ethyl ether	027879-07-8	0-5.0
  Pentaethylene glycol, monobutyl ether	023601-39-0	0-5.0
  Pentaethylene glycol	004792-15-8	0-10.0
  Disodium phosphate	007558-79-4	0-5.0
  Diisopropanolamine	000110-97-4	0-5.0

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned ID numbers (with 6 leading zeros or nines, e.g., 000000-xx-x or 999999-xx-x) for blends and chemicals that do not have CAS numbers.

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Butoxytriglycol	000143-22-6	205-592-6	20.0-75.0	H318 ------- No
  Methoxytriglycol	000112-35-6	--	0-30.0	-------- ------- ---- No
  Ethoxytriglycol	000112-50-5	--	0-40.0	-------- ------- ---- No
  Tetraethylene glycol, monobutyl ether	001559-34-8	216-322-1	0-15.0	-------- ------- ---- No
  Diethylene glycol monobutyl ether	000112-34-5	203-961-6	1-30.0	H319 P264, P280, P305+P351+P338, P337+P313 No
  Diethylene glycol ethyl ether	000111-90-0	203-919-7	0-2.0	-------- ------- ---- No
  Tetraethylene glycol	000112-60-7	--	0-20.0	-------- ------- ---- No
  Diethylene glycol	000111-46-6	203-872-2	0-60.0	H302 ------- No
  Triethylene glycol	000112-27-6	203-953-2	0-20.0	-------- ------- ---- No
  Glycols, polyethylene	025322-68-3	--	0-20.0	-------- ------- ---- No
  PEG-6 methyl ether	009004-74-4	--	0-20.0	-------- ------- ---- No
  Polyethylene glycol, monobutyl ester	009004-77-7	--	0-20.0	-------- ------- ---- No
  Polyethylene glycol ethyl ether	027879-07-8	--	0-5.0	-------- ------- ---- No
  Pentaethylene glycol, monobutyl ether	023601-39-0	245-774-2	0-5.0	-------- ------- ---- No
  Pentaethylene glycol	004792-15-8	225-341-4	0-10.0	-------- ------- ---- No
  Disodium phosphate	007558-79-4	231-448-7	0-5.0	-------- ------- ---- No
  Diisopropanolamine	000110-97-4	203-820-9	0-5.0	H319 ------- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • View Material Safety Data Sheet(MSDS)

    • Date that MSDS was issued by manufacturer of product. MSDS DATE :

      December 20, 2011

    • 	Health	Flammability	Reactivity
      HMIS HMIS RATING	1	2	0

    • Warnings

      
      Eye contact may cause irritation with possible corneal injury. May cause mild skin irritation or sensitization. Harmful if absorbed through the skin. Breathing high concentrations of vapors or mists may cause irritation, headache, dizziness, drowsiness, nausea, loss of sense of balance and visual disturbances. Swallowing may cause gastrointestinal disturbances including irritation, abdominal pain, back pain, nausea, vomiting, diarrhea, headache, dizziness, drowsiness, nausea, visual disturbances, decreased urine production, malaise, unconsciousness and liver or kidney damage. May cause chronic effects.

      
      

    • Acute health effects

      
      From MSDS:
      
      Hazards Identification
      
      Emergency Overview
      
      Eye contact may cause irritation with possible corneal injury. May cause mild skin irritation or sensitization. Harmful if absorbed through the skin. Breathing high concentrations of vapors or mists may cause irritation, headache, dizziness, drowsiness, nausea, loss of sense of balance and visual disturbances. Swallowing may cause gastrointestinal disturbances including irritation, abdominal pain, back pain, nausea, vomiting, diarrhea, headache, dizziness, drowsiness, nausea, visual disturbances, decreased urine production, malaise, unconsciousness and liver or kidney damage. May cause chronic effects.
      
      Potential Health Effects
      
      Inhalation: None expected from short term exposures at ambient temperatures. At elevated temperatures, product may cause respiratory irritation, headache, dizziness, drowsiness, nausea, loss of sense of balance and visual disturbances. High concentrations of vapors at ambient temperatures may cause lung injury, liver dysfunction or kidney damage.
      
      Skin contact: Prolonged or repeated exposure may cause mild irritation with redness and discomfort. Prolonged contact may cause defatting or drying of the skin.
      
      Skin absorption: Prolonged or widespread contact may result in the absorption of potentially harmful amounts resulting in effects similar to those listed under ingestion. Massive contact with damaged skin or with material sufficiently hot to burn the skin may result in absorption of potentially lethal amounts.
      
      Eye contact: May cause irritation with tearing, blurred vision and possible corneal damage.
      
      Ingestion: Ingestion may cause abdominal pain, back pain, nausea, vomiting, diarrhea, headache, dizziness, drowsiness, nausea, visual disturbances, decreased urine production, malaise, cardiopulmonary effects (metabolic acidosis), unconsciousness and liver or kidney damage.
      
      Medical conditions aggravated by exposure: May aggravate pre-existing skin, blood, lung, liver and kidney disorders.
      
      
      
       

      
      

    • Chronic health effects

      
      From MSDS:
      
      Prolonged or repeated skin contact with this product may possibly lead to irritation and dermatitis. Prolonged or repeated exposures may cause damage to the central nervous system, blood, lung, liver or kidneys. Adverse reproductive effects may also occur.
      
      
      
       

      
      

    • Carcinogenicity

      
      Respirable crystalline silica is listed by both NTP and IARC as a carcinogen. None of the other components of this product are listed as a carcinogen or suspected carcinogen by IARC, NTP, ACGIH or OSHA.
      
      
      
      
      
      
      
       

      
      

    • Handling information

      
      Avoid eye contact. Avoid prolonged skin contact. Avoid breathing vapors and mists. Use with adequate ventilation. Wash exposed skin thoroughly with soap and water after use. Keep away from excessive heat and open flames. Do not add nitrites or other nitrosating agents. Nitrosamine, which may cause cancer, may be formed. Keep containers closed when not in use. Store in a cool, dry area. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without any obvious ignition sources. Spills of this product on hot, fibrous insulation may result in spontaneous combustion. Empty containers retain product residue and may be hazardous. Do not cut, weld, drill, etc. containers, even empty. Do not reuse empty containers unless properly cleaned.
      
      
      
      
      
      
      
      
      
       

      
      

    • Disposal information

      
      Dispose of product in accordance with all local, state/provincial and federal regulations.
      
      
      
      
      
       

      
      

    • California Prop. 65 Warning

      
      This product does not contain chemicals regulated under California Proposition 65.

      
      

    • First Aid

      
      Inhalation: Remove to fresh air if effects occur and seek medical attention.
      
      Skin contact: Remove contaminated clothing. Wash all affected and exposed areas with soap and water. If skin irritation or redness develops or persists, seek medical attention.
      
      Eye contact: Exposed eyes should be immediately flushed with copious amounts of water using a steady stream for a minimum of 15 minutes. If irritation, pain, swelling or tearing develop, seek medical attention.
      
      Ingestion: If swallowed, get immediate medical advice by calling a Poison Control Center or hospital emergency room. If advice is not available, take victim and product container to the nearest emergency treatment center or hospital. Do not attempt to give anything by mouth to an unconscious person.
      
      Notes to Physician: It is estimated that the lethal oral dose of diethylene glycol in adults is 1.0-1.2 ml/kg. Diethylene glycol may cause an elevated anion-gap metabolic acidosis and renal tubular injury. Liver injury may occur, but not as severe as kidney injury. The signs and symptoms in diethylene glycol poisoning are those of metabolic acidosis, CNS depression and kidney injury. Urinalysis may show albuminuria, hematuria and oxaluria. The current medical management of diethylene glycol poisoning includes elimination of diethylene glycol, correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and follow-up urinalysis and clinical chemistry. There should be particular emphasis on acidbase balance, and liver and kidney function tests. For severe and/or deteriorating cases, hemodialyis may be required. Dialysis should be considered for patients who have severe metabolic acidosis, or compromise of renal function. There is no conclusive evidence that ethanol treatment will be beneficial. 4-Methyl pyrazole (Fomepizole) shows some promise as treatment because of its apparent lack of toxicity. Consult your poison control center.
      
      
      
       

      
      

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