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CPID

Health effects of consumer products

Clairol Natural Instincts for Men Haircolor, Brown Black-Old Product

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned ID numbers (with 6 leading zeros or nines, e.g., 000000-xx-x or 999999-xx-x) for blends and chemicals that do not have CAS numbers.

  CAS No./ID

  Percent of chemical in preparation.

  % Conc.

  Silk protein, hydrolyzed	096690-41-4	Conditioner
  1-Naphthol	000090-15-3	Colorant
  3-Aminophenol	000591-27-5	Colorant
  p-Phenylenediamine	000106-50-3	Colorant
  Ethylenediaminetetraacetic acid (EDTA)	000060-00-4	Colorant
  Fragrance(s)/perfume(s)	000000-00-1	Conditioner
  Diethylene glycol ethyl ether	000111-90-0	Conditioner
  Wheat protein, hydrolyzed	070084-87-6	Conditioner
  Chamomile extract	084649-86-5	Conditioner
  Jojoba wax	061789-91-1	Colorant
  Citric acid	000077-92-9	Colorant
  Lactic acid	000050-21-5	Conditioner
  Cocoamidopropylbetaine	061789-40-0	Colorant
  Monoethanolamine (MEA)	000141-43-5	Colorant
  Disodium EDTA	000139-33-3	Developer
  Water	007732-18-5	Developer
  Cetyl alcohol	036653-82-4	Developer
  Alcohols, C16-18, ethoxylated	068439-49-6	Conditioner
  Tribehenin	018641-57-1	Conditioner
  Octyl methoxycinnamate	005466-77-3	Conditioner
  Tocopherol	000059-02-9	Conditioner
  Wheat protein, hydrolyzed	070084-87-6	Conditione
  American ginseng extract	090045-38-8	Colorant
  Lactic acid	000050-21-5	Conditione
  Fragrance(s)/perfume(s)	000000-00-1	Conditione
  Disodium phosphate	007558-79-4	Conditioner
  Propylene glycol	000057-55-6	Colorant
  Linoleamidopropyl dimethylamine dimer dilinoleate	000000-43-8	Conditioner
  Amodimethicone	071750-80-6	Conditioner
  Water	007732-18-5	Conditione
  Alcohols, C16-18, ethoxylated	068439-49-6	Conditione
  Cetrimonium chloride	000112-02-7	Conditioner
  Aloe barbadensis extract	094349-62-9	Colorant
  Panthenol	000081-13-0	Colorant
  Chamomile extract	084649-86-5	Conditione
  Silk protein, hydrolyzed	096690-41-4	Conditione
  Stearyl alcohol	000112-92-5	Developer
  Trideceth-12	024938-91-8	Conditioner
  Diethylene glycol ethyl ether	000111-90-0	Conditione
  2-Phenoxyethanol	000122-99-6	Conditioner
  Propylparaben	000094-13-3	Conditioner
  Methylparaben	000099-76-3	Conditioner
  Water	007732-18-5	Developer
  Behentrimonium chloride	017301-53-0	Colorant
  Panthenol	000081-13-0	Colorant
  American ginseng extract	090045-38-8	Colorant
  Tocopheryl acetate	007695-91-2	Colorant
  Aloe barbadensis extract	094349-62-9	Colorant
  Propylene glycol	000057-55-6	Colorant
  Polysorbate 20	009005-64-5	Colorant
  Isoascorbic acid	000089-65-6	Colorant
  Sodium sulfite	007757-83-7	Colorant
  Resorcinol	000108-46-3	Colorant
  N,N-bis(2-Hydroxyethyl)-p-phenylenediamine sulfate	063886-75-9	Colorant
  Cetostearyl alcohol	067762-27-0	Developer
  4-Amino-2-hydroxytoluene	002835-95-2	Colorant
  Nonoyl Nonoxynol-49	009014-93-1	Colorant
  Nonylphenyl polyethoxylate	009016-45-9	Developer
  Acrylates copolymer (unspecified)	999999-47-4	Developer
  Acrylates/Steareth-20 Methacrylate copolymer	000000-50-0	Developer
  Cetyl alcohol	036653-82-4	Developer
  Etidronic acid	002809-21-4	Developer
  Stearyl alcohol	000112-92-5	Developer
  Hydrogen peroxide	007722-84-1	Developer
  Nonoxynol-9	026571-11-9	Developer
  Cetostearyl alcohol	067762-27-0	Developer
  PEG-40 stearate	009004-99-3	Developer
  Castor oil, sulfated	008002-33-3	Developer
  2-Methylresorcinol	000608-25-3	Colorant

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned ID numbers (with 6 leading zeros or nines, e.g., 000000-xx-x or 999999-xx-x) for blends and chemicals that do not have CAS numbers.

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Silk protein, hydrolyzed	096690-41-4	306-235-8	Conditioner	-------- ------- ---- No
  1-Naphthol	000090-15-3	201-969-4	Colorant	H312, H302, H335, H318 ------- No
  3-Aminophenol	000591-27-5	209-711-2	Colorant	H332, H301, H411 ------- No
  p-Phenylenediamine	000106-50-3	203-404-7	Colorant	H331 H311 H301 H319 H317 H410 ------- No
  Ethylenediaminetetraacetic acid (EDTA)	000060-00-4	200-449-4	Colorant	H319 ------- No
  Fragrance(s)/perfume(s)	000000-00-1	--	Conditioner	-------- ------- ---- No
  Diethylene glycol ethyl ether	000111-90-0	203-919-7	Conditioner	-------- ------- ---- No
  Wheat protein, hydrolyzed	070084-87-6	--	Conditioner	-------- ------- ---- No
  Chamomile extract	084649-86-5	283-467-5	Conditioner	-------- ------- ---- No
  Jojoba wax	061789-91-1	296-292-4	Colorant	-------- ------- ---- No
  Citric acid	000077-92-9	201-069-1	Colorant	H319 P264, P280, P305, P351, P338, P337, P313 No
  Lactic acid	000050-21-5	200-018-0	Conditioner	H315, H318 P264, P280, P302+P352, P305+P351+P338, P310, P321, 332+P313, P362 No
  Cocoamidopropylbetaine	061789-40-0	263-058-8	Colorant	-------- ------- ---- No
  Monoethanolamine (MEA)	000141-43-5	205-483-3	Colorant	H302, H312, H332, H314, H335 ------- No
  Disodium EDTA	000139-33-3	205-358-3	Developer	-------- ------- ---- No
  Water	007732-18-5	231-791-2	Developer	-------- ------- ---- No
  Cetyl alcohol	036653-82-4	253-149-0	Developer	-------- ------- ---- No
  Alcohols, C16-18, ethoxylated	068439-49-6	500-212-8	Conditioner	-------- ------- ---- No
  Tribehenin	018641-57-1	242-471-7	Conditioner	-------- ------- ---- No
  Octyl methoxycinnamate	005466-77-3	226-775-7	Conditioner	-------- ------- ---- No
  Tocopherol	000059-02-9	--	Conditioner	-------- ------- ---- No
  Wheat protein, hydrolyzed	070084-87-6	--	Conditione	-------- ------- ---- No
  American ginseng extract	090045-38-8	289-898-5	Colorant	-------- ------- ---- No
  Lactic acid	000050-21-5	200-018-0	Conditione	H315, H318 P264, P280, P302+P352, P305+P351+P338, P310, P321, 332+P313, P362 No
  Fragrance(s)/perfume(s)	000000-00-1	--	Conditione	-------- ------- ---- No
  Disodium phosphate	007558-79-4	231-448-7	Conditioner	-------- ------- ---- No
  Propylene glycol	000057-55-6	200-338-0	Colorant	-------- ------- ---- No
  Linoleamidopropyl dimethylamine dimer dilinoleate	000000-43-8	--	Conditioner	-------- ------- ---- No
  Amodimethicone	071750-80-6	-	Conditioner	-------- ------- ---- No
  Water	007732-18-5	231-791-2	Conditione	-------- ------- ---- No
  Alcohols, C16-18, ethoxylated	068439-49-6	500-212-8	Conditione	-------- ------- ---- No
  Cetrimonium chloride	000112-02-7	203-928-6	Conditioner	-------- ------- ---- No
  Aloe barbadensis extract	094349-62-9	305-181-2	Colorant	-------- ------- ---- No
  Panthenol	000081-13-0	201-327-3	Colorant	-------- ------- ---- No
  Chamomile extract	084649-86-5	283-467-5	Conditione	-------- ------- ---- No
  Silk protein, hydrolyzed	096690-41-4	306-235-8	Conditione	-------- ------- ---- No
  Stearyl alcohol	000112-92-5	204-017-6	Developer	-------- ------- ---- No
  Trideceth-12	024938-91-8	-	Conditioner	-------- ------- ---- No
  Diethylene glycol ethyl ether	000111-90-0	203-919-7	Conditione	-------- ------- ---- No
  2-Phenoxyethanol	000122-99-6	204-589-7	Conditioner	H302, H319 P264, P280, P330, P337+P313, P305, P351, P338 No
  Propylparaben	000094-13-3	202-307-7	Conditioner	-------- ------- ---- No
  Methylparaben	000099-76-3	202-785-7	Conditioner	-------- ------- ---- No
  Water	007732-18-5	231-791-2	Developer	-------- ------- ---- No
  Behentrimonium chloride	017301-53-0	241-327-0	Colorant	-------- ------- ---- No
  Panthenol	000081-13-0	201-327-3	Colorant	-------- ------- ---- No
  American ginseng extract	090045-38-8	289-898-5	Colorant	-------- ------- ---- No
  Tocopheryl acetate	007695-91-2	231-710-0	Colorant	-------- ------- ---- No
  Aloe barbadensis extract	094349-62-9	305-181-2	Colorant	-------- ------- ---- No
  Propylene glycol	000057-55-6	200-338-0	Colorant	-------- ------- ---- No
  Polysorbate 20	009005-64-5	--	Colorant	-------- ------- ---- No
  Isoascorbic acid	000089-65-6	201-928-0	Colorant	-------- ------- ---- No
  Sodium sulfite	007757-83-7	231-821-4	Colorant	-------- ------- ---- No
  Resorcinol	000108-46-3	108-46-3	Colorant	H302, H315, H319, H400 ------- No
  N,N-bis(2-Hydroxyethyl)-p-phenylenediamine sulfate	063886-75-9	--	Colorant	-------- ------- ---- No
  Cetostearyl alcohol	067762-27-0	267-008-6	Developer	-------- ------- ---- No
  4-Amino-2-hydroxytoluene	002835-95-2	220-618-6	Colorant	-------- ------- ---- No
  Nonoyl Nonoxynol-49	009014-93-1	-	Colorant	-------- ------- ---- No
  Nonylphenyl polyethoxylate	009016-45-9	--	Developer	-------- ------- ---- No
  Acrylates copolymer (unspecified)	999999-47-4	--	Developer	-------- ------- ---- No
  Acrylates/Steareth-20 Methacrylate copolymer	000000-50-0	--	Developer	-------- ------- ---- No
  Cetyl alcohol	036653-82-4	253-149-0	Developer	-------- ------- ---- No
  Etidronic acid	002809-21-4	220-552-8	Developer	-------- ------- ---- No
  Stearyl alcohol	000112-92-5	204-017-6	Developer	-------- ------- ---- No
  Hydrogen peroxide	007722-84-1	231-765-0	Developer	H271, H332, H302, H314 ------- No
  Nonoxynol-9	026571-11-9	--	Developer	-------- ------- ---- No
  Cetostearyl alcohol	067762-27-0	267-008-6	Developer	-------- ------- ---- No
  PEG-40 stearate	009004-99-3	--	Developer	-------- ------- ---- No
  Castor oil, sulfated	008002-33-3	232-306-7	Developer	-------- ------- ---- No
  2-Methylresorcinol	000608-25-3	210-155-8	Colorant	-------- ------- ---- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that MSDS was issued by manufacturer of product. MSDS DATE :

      January 25, 2002

    • 	Health	Flammability	Reactivity
      HMIS HMIS RATING	N	N	N

    • Warnings

      This product contains ingredients that may cause skin irritation on certain individuals, and a preliminary test according to accompanying directions should first be made. This product must not be used for dyeing the eyelashes or eyebrows; to do so may cause blindness.

    • Acute health effects

      From MSDS HEALTH HAZARDS AND HAZARD DATA FOR THE COLORANT-(MSDS 1/25/02) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Unmixed oxidation haircolors are eye irritants. When oxidation haircolors are mixed with developers (hydrogen peroxide), the mixture may cause severe irritation and possible permanent eye injury. SKIN CONTACT: May cause skin irritation or sensitization in sensitive individuals. INHALATION: Inhalation of vapors may result in respiratory irritation. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HEALTH HAZARDS AND HAZARD DATA FOR THE DEVELOPER-(MSDS 9/4/01) The TLV of the mixture has not been established. EYE CONTACT: CAUTION. Developers are eye irritants. May cause severe irritation and possible permanent eye injury. SKIN CONTACT: Prolonged contact with skin may bleach it and cause burns. INHALATION: Not likely to be inhaled. INGESTION: Moderately toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products. HEALTH HAZARDS AND HAZARD DATA FOR THE CONDITIONER-(MSDS 9/4/01) The TLV of the mixture has not been established. EYE CONTACT: Potential eye irritant. SKIN CONTACT: Potential skin irritant. INHALATION: Not applicable. INGESTION: Practically non toxic. ROUTE OF ENTRY Inhalation: No; Ingestion: Yes; Skin: Yes. Pre-existing dermatitis would likely be made worse by exposure to these products.

    • Chronic health effects

      From MSDS HAZARD DATA FOR THE COLORANT A composite mixture of oxidative dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. These results show that these ingredients pose no carcinogenic hazard to humans under normal conditions of exposure. In topical studies, other than limited effect of treated skin, no target organ toxicity was observed in respect to any organ. Pre-existing dermatitis would likely be made worse by exposure to these products. Bronchitis may be aggravated by irritant vapors. HAZARD DATA FOR THE DEVELOPER When developers were mixed with hair dyes and applied to the skin of animals for prolonged periods, no adverse effects on growth, reproduction or general health were observed. Prolonged contact with skin may result in bleaching and irritation of skin. Target Organs: Skin Pre-existing dermatitis would likely be made worse by exposure to these products. HAZARD DATA FOR THE CONDITIONER For purposes of chronic exposure under the OSHA Hazard Communication Standard, this is an untested mixture. These products have been used extensively by consumers and Worldwide Beauty Care is not aware of any significant adverse effects. Target Organs: These products contain ingredients which have been shown to affect tissues or organs when fed at high levels of exposure in animal studies not encountered in normal use. Target Organs identified in animal studies are as follows: Glycerin:- Kidney, Liver; Propylene Glycol:- CNS; Isopropyl Alcohol:- CNS. Pre-existing dermatitis would likely be made worse by exposure to these products.

    • Carcinogenicity

      From MSDS Not listed as carcinogen by NTP, IARC or OSHA.

    • Handling information

      From MSDS COLORANT Do not expose to sunlight. Keep away from radiators and heat. Do not store any haircolor after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. DEVELOPER Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original tightly capped containers away from sunlight, heat sparks and flame. Do not store any tint, lightener, lotion or bleach powder after it has been mixed with developer; container may rupture. Never return unused material to original container. Empty containers should be rinsed with water before discarding. Keep out of reach of children. Other precautions: Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. CONDITIONER No precautions necessary.

    • Disposal information

      From MSDS Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA. Additionally, disposal should be in accordance with all applicable Local, State and Federal regulations.

    • First Aid

      From MSDS Eye Contact: Remove contact lenses, if used. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center.

.